A versatile "on-off-on" quinoline pyrazoline hybrid for sequential detection of Cu2+ and S- ions towards bio imaging and tannery effluent monitoring

被引:17
|
作者
Subashini, Gopalan [1 ]
Saravanan, Arjunan [2 ]
Shyamsivappan, Selvaraj [3 ]
Arasakumar, Thangaraj [3 ]
Mahalingam, Viswanathan [4 ]
Shankar, Ramasamy [5 ]
Mohan, Palathurai Subramaniam [3 ]
机构
[1] PSGR Krishnammal Coll Women, Dept Chem, Coimbatore 641004, Tamil Nadu, India
[2] DRDO BU CLS, Bharathiar Univ Campus, Coimbatore 641046, Tamil Nadu, India
[3] Bharathiar Univ, Dept Chem, Coimbatore 641046, Tamil Nadu, India
[4] Sri Krishna Coll Engn & Technol, Coimbatore 641008, Tamil Nadu, India
[5] Bharathiar Univ, Dept Phys, Coimbatore 641046, Tamil Nadu, India
关键词
Copper; DFT studies; Fluorescent imaging; Quinoline; Sulphide; Tannery effluent; EFFECTIVE CORE POTENTIALS; SELECTIVE FLUORESCENT SENSOR; MOLECULAR CALCULATIONS; SENSITIVE DETECTION; SULFIDE ANION; AQUEOUS-SOLUTION; NITRIC-OXIDE; TRACE-METALS; COPPER IONS; PROBE;
D O I
10.1016/j.ica.2018.08.012
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A quinoline-pyrazoline (QTP) module has been designed, synthesized and characterized as a fluorescence sensor for sequential detection of Cu2+ and S2- ions. The dual functional probe showed "on-off-on" property through displacement approach and because of fast kinetics between Cu2+ and S2- ion. Fluorescence imaging experiments with MG 63 cell lines exclusively demonstrate the applicability of Cu (II) imaging in biological systems. It is also used for the real-time analysis of sulphide ion in tannery effluent for environmental monitoring.
引用
收藏
页码:173 / 179
页数:7
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