Photoluminescence of bulks and thin films of Eu3+-doped organic/inorganic hybrids

被引：16
作者：
Pecoraro, E. [1 ,2 ]
Ferreira, R. A. Sa [1 ]
Molina, C. [2 ]
Ribeiro, S. J. L. [2 ]
Messsaddeq, Y. [2 ]
Carlos, L. D. [1 ]
机构：
[1] Univ Aveiro, CICECO, Dept Phys, P-3810193 Aveiro, Portugal
[2] UNESP, Inst Chem, BR-14801970 Araraquara, SP, Brazil
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 2008年 / 451卷 / 1-2期
关键词：
europium; photoluminescence; organic-inorganic hybrids; thin films;
D O I：
10.1016/j.jallcom.2007.04.123
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Organic-inorganic hybrids formed by polyether-based chains grafted to both ends to a siliceous backbone through urea cross-linkages (-NHC=O)NH-), named di-ureasil, have been used as host for incorporation of Eu3+ in the form of EuCl3. The bulks and the thin films, both optically transparent, were characterized by excitation, absorption and emission spectroscopy. Photoluminescence results point out that the Eu3+ ions occupy, at least, two distinct local environments. Besides, the processing method (thin films or bulks) has influence on the energy levels of the hybrid host probably due to the lower degree of organization of the thin films structure. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：136 / 139
页数：4
相关论文
共 50 条
  • [21] Spectroscopic and photoluminescence characterization of Eu3+-doped monoclinic KY(WO4)2 crystal
    Loiko, P. A.
    Dashkevich, V. I.
    Bagaev, S. N.
    Orlovich, V. A.
    Yasukevich, A. S.
    Yumashev, K. V.
    Kuleshov, N. V.
    Dunina, E. B.
    Kornienko, A. A.
    Vatnik, S. M.
    Pavlyuk, A. A.
    JOURNAL OF LUMINESCENCE, 2014, 153 : 221 - 226
  • [22] Synthesis and photoluminescence of Eu3+-doped Y2Sn2O7 nanocrystals
    Lu, ZG
    Wang, JW
    Tang, YG
    Li, YD
    JOURNAL OF SOLID STATE CHEMISTRY, 2004, 177 (09) : 3075 - 3079
  • [23] Effect of Structural Changes Induced by Annealing Atmospheres on Luminescence of Eu2+- and Eu3+-Doped AlN Thin Films
    Miyano, Kazuto
    Qian, Yingda
    Kaku, Shinichiro
    Zhao, Xinwei
    Murayama, Mariko
    PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 2025,
  • [24] Photoluminescence of Eu3+-doped nanosized microporous titanosilicate -: A structural analogue of the mineral pharmacosiderite
    Ferdov, Stanislav
    Ferreira, Rute A. Sa
    Lin, Zhi
    JOURNAL OF ALLOYS AND COMPOUNDS, 2008, 451 (1-2) : 125 - 127
  • [25] Annealing effects on the microstructure and photoluminescence of Eu3+-doped GdVO4 powders
    Jovanovic, Dragana J.
    Antic, Zeljka
    Krsmanovic, Radenka M.
    Mitric, Miodrag
    Dordevic, Vesna
    Bartova, Barbora
    Dramicanin, Miroslav D.
    OPTICAL MATERIALS, 2013, 35 (10) : 1797 - 1804
  • [26] Preparation and photoluminescence properties of Eu3+-doped ZrO2 nanotube arrays
    Wang, Mingli
    Wang, Xixin
    Lin, Jing
    Ning, Xuewen
    Yang, Xiaojing
    Zhang, Xinghua
    Zhao, Jianling
    CERAMICS INTERNATIONAL, 2015, 41 (07) : 8444 - 8450
  • [27] Red-orange photoluminescence and dielectric relaxation of Eu3+-doped Bi2Ti2O7 pyrochlore structure thin films
    Li, Fanfan
    Liu, Xiang
    Zhao, Jianxiong
    Liu, Ling
    He, Shuai
    Bao, Dinghua
    MATERIALS CHEMISTRY AND PHYSICS, 2015, 162 : 801 - 806
  • [28] The photoluminescence properties of undoped & Eu-doped ZnO thin films grown by RF sputtering on sapphire and silicon substrates
    Ahmed, Samah M.
    Szymanski, Paul
    El-Sayed, Mostafa A.
    Badr, Yehia
    El-Nadi, Lotfia M.
    APPLIED SURFACE SCIENCE, 2015, 359 : 356 - 363
  • [29] Structural and luminescent characteristics of pulsed laser deposited Eu3+-doped Y2O3 thin films
    Anoopy, G.
    Minikrishnaz, K.
    Jayaraj, M. K.
    PHILOSOPHICAL MAGAZINE, 2012, 92 (14) : 1777 - 1787
  • [30] Phase transition and photoluminescence properties of Eu3+-doped ZnMoO4 red phosphors
    Zhou Yu
    Zhang ZhiJie
    Chu YaoQing
    Pan YunFang
    You MingJiang
    Zheng TingTing
    Xu JiaYue
    SCIENCE CHINA-TECHNOLOGICAL SCIENCES, 2017, 60 (10) : 1473 - 1479
12345