A new route to MFI/MCM-41 micro-mesoporous composite

被引:3
作者
Dedov, A. G. [1 ]
Loktev, A. S. [1 ]
Karavaev, A. A. [1 ]
Baranchikov, A. E. [2 ]
Ivanov, V. K. [2 ]
Tyumenova, S. I. [1 ]
Moiseev, I. I. [1 ]
机构
[1] Gubkin Russian State Univ Oil & Gas, Leninskii Pr 65, Moscow 119991, Russia
[2] Russian Acad Sci, Kurnakov Inst Inorgan & Gen Chem, Leninskii Pr 31, Moscow 119991, Russia
基金
俄罗斯基础研究基金会;
关键词
METHANOL DEHYDRATION; BENZENE ALKYLATION; MOLECULAR-SIEVES; DIMETHYL ETHER; H-ZSM-5/MCM-41; ETHYLBENZENE; CATALYST; ETHANE;
D O I
10.1134/S0012500816060021
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new route to MFI/MCM-41 micro-mesoporous composite is reported. This composite was synthesized for the first time by the hydrothermal microwave two-template method, and the stage of crystallization was carried out for the first time at 190A degrees C. The developed procedure makes it possible to significantly reduce the time of synthesis of the MFI/MCM-41 micro-mesoporous composite as compared with the known methods.
引用
收藏
页码:179 / 182
页数:4
相关论文
共 15 条
[1]  
Baerlocher Ch., 2007, ATLAS ZEOLITE STRUCT, V6th
[2]   Overview and Industrial Assessment of Synthesis Strategies towards Zeolites with Mesopores [J].
Chal, Robin ;
Gerardin, Corine ;
Bulut, Metin ;
van Donk, Sander .
CHEMCATCHEM, 2011, 3 (01) :67-81
[3]  
Dedov A.G., 2016, RF Patent Application, Patent No. 2016102971
[4]   Investigation of synthesizing MCM-41/ZSM-5 composites [J].
Huang, LM ;
Guo, WP ;
Deng, P ;
Xue, ZY ;
Li, QZ .
JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (13) :2817-2823
[5]  
Ionin D.A., 2015, NEFTEKHIMIYA, V55, P119
[6]   Composites of micro- and mesoporous materials:: simultaneous syntheses of MFI/MCM-41 like phases by a mixed template approach [J].
Karlsson, A ;
Stöcker, M ;
Schmidt, R .
MICROPOROUS AND MESOPOROUS MATERIALS, 1999, 27 (2-3) :181-192
[7]  
Khadzhiev S.N., 2014, NEFTEKHIMIYA, V5, P243
[8]   Synthesis of gasoline from syngas via dimethyl ether [J].
Kolesnichenko, N. V. ;
Kitaev, L. E. ;
Bukina, Z. M. ;
Markova, N. A. ;
Yushchenko, V. V. ;
Yashina, O. V. ;
Lin, G. I. ;
Rozovskii, A. Ya. .
KINETICS AND CATALYSIS, 2007, 48 (06) :789-793
[9]   The discovery of mesoporous molecular sieves from the twenty year perspective [J].
Kresge, Charles T. ;
Roth, Wieslaw J. .
CHEMICAL SOCIETY REVIEWS, 2013, 42 (09) :3663-3670
[10]   Micro-mesoporous composite molecular sieves H-ZSM-5/MCM-41 for methanol dehydration to dimethyl ether: Effect of SiO2/Al2O3 ratio in H-ZSM-5 [J].
Li, Hansheng ;
He, Shichao ;
Ma, Ke ;
Wu, Qin ;
Jiao, Qingze ;
Sun, Kening .
APPLIED CATALYSIS A-GENERAL, 2013, 450 :152-159