Vapor-liquid equilibria of systems containing acetic acid and gaseous components. Measurements and calculations by a cubic equation of state

被引:32
作者
Jonasson, A [1 ]
Persson, O [1 ]
Rasmussen, P [1 ]
Soave, GS [1 ]
机构
[1] Tech Univ Denmark, Dept Chem Engn, Engn Res Ctr IVCSEP, DK-2800 Lyngby, Denmark
关键词
method of calculation; vapor-liquid equilibria; equation of state; data; association; acetic acid;
D O I
10.1016/S0378-3812(98)00397-5
中图分类号
O414.1 [热力学];
学科分类号
摘要
Isothermal pressure-composition VLE data have been measured for four systems containing acetic acid and a gaseous component. The gaseous components are carbon monoxide, carbon dioxide, hydrogen and methane. The measurements were made in a static cell and the compositions of the gas and the liquid phases were measured by a gas chromatograph. A new correlation model (ACE, Association + Cubic Equation of state) was developed. It is based on a cubic equation of state and a model for the dimerization of acetic acid. It was applied to correlate the experimetnal VLE data with good results. (C) 1998 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:67 / 94
页数:28
相关论文
共 50 条
  • [41] Predicting the excess enthalpies and vapor-liquid equilibria of multicomponent systems containing ether and hydrocarbons
    Peng, DY
    Wang, ZH
    Benson, GC
    Lu, BCY
    FLUID PHASE EQUILIBRIA, 2001, 182 (1-2) : 217 - 227
  • [42] Vapor-liquid equilibria calculations for components of natural gas using Huron-Vidal mixing rules
    Cavalcante, Antonio
    de Oliveira, Ingrid Azevedo
    Segtovich, Iuri Soter Viana
    Barreto Jr, Amaro Gomes
    Tavares, Frederico Wanderley
    BRAZILIAN JOURNAL OF CHEMICAL ENGINEERING, 2023, 41 (4) : 949 - 963
  • [43] A new mixing rule for cubic equations of state and its application to vapor-liquid equilibria of polymer solutions
    Zhong, CL
    Masuoka, H
    FLUID PHASE EQUILIBRIA, 1996, 123 (1-2) : 59 - 69
  • [44] Vapor-liquid equilibria of LNG and gas condensate mixtures by the Nasrifar-Moshfeghian equation of state
    Nasrifar, K
    Moshfeghian, M
    FLUID PHASE EQUILIBRIA, 2002, 200 (01) : 203 - 216
  • [45] Correlation of Vapor-Liquid Equilibria of Binary Systems Containing Carboxylic Acid by Using Wilson Equation with Parameters Estimated from Pure-Component Properties
    Kobuchi, Shigetoshi
    Takakura, Kei
    Yonezawa, Setsuko
    Fukuchi, Kenji
    Arai, Yasuhiko
    JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 2013, 46 (02) : 100 - 106
  • [46] Vapor-liquid equilibrium correlations for systems containing amines using a lattice fluid equation of state with hydrogen bonding
    Alexander Breitholz
    Ki-Pung Yoo
    Jong Sung Lim
    Chul Soo Lee
    Jeong Won Kang
    Korean Journal of Chemical Engineering, 2008, 25 : 833 - 837
  • [47] Vapor-liquid equilibrium correlations for systems containing amines using a lattice fluid equation of state with hydrogen bonding
    Breithotz, Alexander
    Yoo, Ki-Pung
    Lim, Jong Sung
    Lee, Chul Soo
    Kang, Jeong Won
    KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2008, 25 (04) : 833 - 837
  • [48] Vapor-liquid equilibrium predictions of refrigerant mixtures from a cubic equation of state with a GE-EoS mixing rule
    Ioannidis, S
    Knox, DE
    FLUID PHASE EQUILIBRIA, 1997, 140 (1-2) : 17 - 35
  • [49] Measurement and Prediction of Vapor-Liquid Equilibria in Ternary Systems Containing an Organic Component, Cyclohexylamine, and Cyclohexanol
    Klauck, Mandy
    Haehnel, Thomas
    Richter, Sandra
    Schmelzer, Juergen
    Kalies, Grit
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2018, 63 (01) : 119 - 126
  • [50] Experimental Measurements and Correlations Isobaric Vapor-Liquid Equilibria for Water plus Acetic Acid plus Sec-butyl Acetate at 101.3 kPa
    Li Ling
    He Yong
    Wu Yanxiang
    Zou Wenhu
    CHINESE JOURNAL OF CHEMICAL ENGINEERING, 2013, 21 (07) : 759 - 765