PRODUCTION OF 5-HYDROXYMETHYLFURFURAL (HMF) VIA FRUCTOSE DEHYDRATION: EFFECT OF SOLVENT AND SALTING-OUT

被引：66

作者：

Gomes, F. N. D. C. ^{[1
]}

Pereira, L. R. ^{[1
]}

Ribeiro, N. F. P. ^{[1
]}

Souza, M. M. V. M. ^{[1
]}

机构：

[1] Univ Fed Rio de Janeiro, Escola Quim, Ctr Tecnol, BR-21941909 Rio De Janeiro, RJ, Brazil

来源：

BRAZILIAN JOURNAL OF CHEMICAL ENGINEERING | 2015年 / 32卷 / 01期

关键词：

5-hydroxymethylfurfural; Dehydration; Fructose; Biphasic system; Salting-out; BIOMASS; CONVERSION; ACID; CHEMICALS; 5-HYDROXYMETHYL-2-FURALDEHYDE; SUGARS; WATER;

D O I：

10.1590/0104-6632.20150321s00002914

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

5-Hydroxymethylfurfural (HMF) is a key renewable platform compound for production of fuels and chemical intermediates. The production of 5-hydroxymethylfurfural (HMF) from fructose dehydration was studied using H3PO4 as catalyst, in organic/water system with different solvents (acetone, 2-butanol and ethyl ether). The effect of fructose concentration, temperature and acid concentration was investigated in acetone/water medium. The increase in fructose concentration favors the formation of condensation products and rehydration products are favored at high acid concentration. The solvents exhibited similar performance when the volume ratio of organic to aqueous phase was 1:1, but when this ratio increases to 2:1, the HMF yield obtained with ether was much lower. NaCl addition to the aqueous phase promoted the extraction of HMF to the organic phase, with an HMF yield of 80% in the case of 2:1 acetone/water medium.

引用

页码：119 / 126

页数：8

共 27 条

[1] Acid-catalyzed production of 5-hydroxymethyl furfural from D-fructose in subcritical water [J].

Asghari, FS ;

Yoshida, H .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2006, 45 (07) :2163-2173

[2] Dehydration of fructose to 5-hydroxymethylfurfural in sub- and supercritical acetone [J].

Bicker, M ;

Hirth, J ;

Vogel, H .

GREEN CHEMISTRY, 2003, 5 (02) :280-284

[3] Process integration for the conversion of glucose to 2,5-furandicarboxylic acid [J].

Boisen, A. ;

Christensen, T. B. ;

Fu, W. ;

Gorbanev, Y. Y. ;

Hansen, T. S. ;

Jensen, J. S. ;

Klitgaard, S. K. ;

Pedersen, S. ;

Riisager, A. ;

Stahlberg, T. ;

Woodley, J. M. .

CHEMICAL ENGINEERING RESEARCH & DESIGN, 2009, 87 (9A) :1318-1327

[4] Technology development for the production of biobased products from biorefinery carbohydrates-the US Department of Energy's "Top 10" revisited [J].

Bozell, Joseph J. ;

Petersen, Gene R. .

GREEN CHEMISTRY, 2010, 12 (04) :539-554

[5] DEHYDRATION REACTIONS OF FRUCTOSE IN NON-AQUEOUS MEDIA [J].

BROWN, DW ;

FLOYD, AJ ;

KINSMAN, RG ;

ROSHANALI, Y .

JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 1982, 32 (10) :920-924

[6] A process for efficient conversion of fructose into 5-hydroxymethylfurfural in ammonium salts [J].

Cao, Quan ;

Guo, Xingcui ;

Guan, Jing ;

Mu, Xindong ;

Zhang, Dongke .

APPLIED CATALYSIS A-GENERAL, 2011, 403 (1-2) :98-103

[7] Production of 5-hydroxymethylfurfural and furfural by dehydration of biomass-derived mono- and poly-saccharides [J].

Chheda, Juben N. ;

Roman-Leshkov, Yuriy ;

Dumesic, James A. .

GREEN CHEMISTRY, 2007, 9 (04) :342-350

[8] Chemical routes for the transformation of biomass into chemicals [J].

Corma, Avelino ;

Iborra, Sara ;

Velty, Alexandra .

CHEMICAL REVIEWS, 2007, 107 (06) :2411-2502

[9] 5-Hydroxymethylfurfural production from sugars and cellulose in acid- and base-catalyzed conditions under hot compressed water [J].

Daorattanachai, Pornlada ;

Namuangruk, Supawadee ;

Viriya-empikul, Nawin ;

Laosiripojana, Navadol ;

Faungnawakij, Kajornsak .

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2012, 18 (06) :1893-1901

[10]

de Souza R.L., 2012, Challenges, V3, P212, DOI [10.3390/challe3020212, DOI 10.3390/CHALLE3020212]

← 1 2 3 →