Electronic, Molecular Weight, Molecular Volume, and Financial Cost-Scaling and Comparison of Two-Photon Absorption Efficiency in Disparate Molecules (Organometallic Complexes for Nonlinear Optics. 48.) - A Response to "Comment on 'Organometallic Complexes for Nonlinear Optics. 45. Dispersion of the Third-Order Nonlinear Optical Properties of Triphenylamine-Cored Alkynylruthenium Dendrimers.' Increasing the Nonlinear Response by Two Orders of Magnitude."

被引:70
|
作者
Schwich, Torsten [1 ]
Cifuentes, Marie P. [1 ]
Gugger, Paul A. [1 ]
Samoc, Marek [2 ]
Humphrey, Mark G. [1 ]
机构
[1] Australian Natl Univ, Res Sch Chem, Canberra, ACT 0200, Australia
[2] Wroclaw Univ Technol, Inst Phys & Theoret Chem, PL-50370 Wroclaw, Poland
关键词
dendrimers; nonlinear optics; organometallics;
D O I
10.1002/adma.201004348
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The two-photon absorption cross-sections of related organometallic and organic dendrimers have been compared using a basket of scaling factors, the results revealing that organometallics are highly competitive as possible nonlinear optical materials viewed from economic, size, and weight perspectives, as well as consideration of π-electron contribution. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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收藏
页码:1433 / 1435
页数:3
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