The chirality, porosity, and ferromagnetism of a 3D nickel glutarate with intersecting 20-membered ring channels

被引：182
作者：
Guillou, N
Livage, C
Drillon, M
Férey, G
机构：
[1] Univ Versailles St Quentin Yvelines, CNRS, UMR 8637, Inst Lavoisier, F-78035 Versailles, France
[2] Inst Phys & Chim Mat Strasbourg, F-67037 Strasbourg, France
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 43期
关键词：
chirality; ferromagnetism; microporous materials; nickel; O ligands;
D O I：
10.1002/anie.200352520
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new dimension to nickel structures: A three-dimensional nickel glutarate, [Ni20{(C5H6O4)20(H 2O)8}]·40 H2O, has been prepared under hydrothermal conditions. Its structure, solved from X-ray powder diffraction, is constructed from interconnected 20-rings, which form a remarkable open network of crossing channels (see picture). It is porous, and exhibits a ferromagnetic long-range ordering below 4 K.
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收藏
页码：5314 / 5317
页数：4
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