An Isoreticular Series of Zinc(II) Metal-Organic Frameworks Derived from Terpyridylcarboxylate Ligands

被引：13
作者：
Young, David C. [1 ]
Yang, Hui [2 ]
Telfer, Shane G. [2 ]
Kruger, Paul E. [1 ]
机构：
[1] Univ Canterbury, MacDiarmid Inst Adv Mat & Nanotechnol, Sch Phys & Chem Sci, Christchurch 8140, New Zealand
[2] Massey Univ, MacDiarmid Inst Adv Mat & Nanotechnol, Inst Fundamental Sci, Palmerston North 1112, New Zealand
来源：
INORGANIC CHEMISTRY | 2017年 / 56卷 / 20期
关键词：
SECONDARY BUILDING UNITS; CARBON-DIOXIDE; POROUS CARBON; NANOPOROUS CARBONS; METHANE STORAGE; ADSORPTION; STABILITY; MOF; CO2; 2,2'/6',2''-TERPYRIDINES;
D O I：
10.1021/acs.inorgchem.7b01632
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
An isoreticular family of seven microporous metal-organic frameworks of the general form [ZnL] have been synthesized, where L is a 4'-substituted 2,2':6',2 ''-terpyridine-4,4 ''-dicarboxylate ligand. Each framework adopts an interpenetrated zeolitic gismondine (gis-c) topology and possesses one-dimensional square channels with ca. 9.0 angstrom apertures running down the crystallographic c axis. Gas adsorption measurements with N-2, H-2, CH4, and CO2 confirm their permanent porosity. The ligand functional groups, which include phenyl, 2-tolyl, 4-chlorophenyl, 4-nitrophenyl, 2-thienyl, 3-thienyl, and 4-pyridyl, line the channel walls and tune the gas adsorption properties of these materials.
引用
收藏
页码：12224 / 12231
页数：8
相关论文
共 54 条
  • [1] SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPOUNDS CONTAINING NITROGEN SULFUR DONOR LIGANDS - THE CRYSTAL AND MOLECULAR-STRUCTURE OF AQUA[1,7-BIS(N-METHYLBENZIMIDAZOL-2'-YL)-2,6-DITHIAHEPTANE]COPPER(II) PERCHLORATE
    ADDISON, AW
    RAO, TN
    REEDIJK, J
    VANRIJN, J
    VERSCHOOR, GC
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (07): : 1349 - 1356
  • [2] Terminology of metal-organic frameworks and coordination polymers (IUPAC Recommendations 2013)
    Batten, Stuart R.
    Champness, Neil R.
    Chen, Xiao-Ming
    Garcia-Martinez, Javier
    Kitagawa, Susumu
    Ohrstrom, Lars
    O'Keeffe, Michael
    Suh, Myunghyun Paik
    Reedijk, Jan
    [J]. PURE AND APPLIED CHEMISTRY, 2013, 85 (08) : 1715 - 1724
  • [3] Different adsorption behaviors of methane and carbon dioxide in the isotypic nanoporous metal terephthalates MIL-53 and MIL-47
    Bourrelly, S
    Llewellyn, PL
    Serre, C
    Millange, F
    Loiseau, T
    Férey, G
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (39) : 13519 - 13521
  • [4] Carrington EJ, 2017, NAT CHEM, V9, P882, DOI [10.1038/nchem.2747, 10.1038/NCHEM.2747]
  • [5] A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability
    Cavka, Jasmina Hafizovic
    Jakobsen, Soren
    Olsbye, Unni
    Guillou, Nathalie
    Lamberti, Carlo
    Bordiga, Silvia
    Lillerud, Karl Petter
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (42) : 13850 - 13851
  • [6] A new family of carbon materials: synthesis of MOF-derived nanoporous carbons and their promising applications
    Chaikittisilp, Watcharop
    Ariga, Katsuhiko
    Yamauchi, Yusuke
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (01) : 14 - 19
  • [7] A more efficient synthesis of 4,4',4"-tricarboxy-2,2':6',2"-terpyridine
    Dehaudt, Jeremy
    Husson, Jerome
    Guyard, Laurent
    [J]. GREEN CHEMISTRY, 2011, 13 (12) : 3337 - 3340
  • [8] Large-Pore Apertures in a Series of Metal-Organic Frameworks
    Deng, Hexiang
    Grunder, Sergio
    Cordova, Kyle E.
    Valente, Cory
    Furukawa, Hiroyasu
    Hmadeh, Mohamad
    Gandara, Felipe
    Whalley, Adam C.
    Liu, Zheng
    Asahina, Shunsuke
    Kazumori, Hiroyoshi
    O'Keeffe, Michael
    Terasaki, Osamu
    Stoddart, J. Fraser
    Yaghi, Omar M.
    [J]. SCIENCE, 2012, 336 (6084) : 1018 - 1023
  • [9] OLEX2: a complete structure solution, refinement and analysis program
    Dolomanov, Oleg V.
    Bourhis, Luc J.
    Gildea, Richard J.
    Howard, Judith A. K.
    Puschmann, Horst
    [J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2009, 42 : 339 - 341
  • [10] Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage
    Eddaoudi, M
    Kim, J
    Rosi, N
    Vodak, D
    Wachter, J
    O'Keeffe, M
    Yaghi, OM
    [J]. SCIENCE, 2002, 295 (5554) : 469 - 472
123456