On the properties of (choline chloride plus lactic acid) deep eutectic solvent with methanol mixtures

被引：47
|
作者：
Alcalde, Rafael [1 ]
Atilhan, Mert [2 ,3 ]
Aparicio, Santiago [1 ]
机构：
[1] Univ Burgos, Dept Chem, Burgos 09001, Spain
[2] Texas A&M Univ Qatar, Dept Chem Engn, Doha, Qatar
[3] Texas A&M Univ, Gas & Fuels Res Ctr, College Stn, TX USA
来源：
JOURNAL OF MOLECULAR LIQUIDS | 2018年 / 272卷
关键词：
Deep eutectic solvents; Intermolecular forces; Methanol; Mixtures; Thermophysics; AQUEOUS MIXTURES; TEMPERATURE-RANGE; GREEN SOLVENTS; IONIC LIQUIDS; DENSITIES; TOXICITY; DESS; BIODEGRADABILITY; ELECTROLYTES; VISCOSITIES;
D O I：
10.1016/j.molliq.2018.10.052
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The binary mixtures formed by choline chloride + lactic acid deep eutectic solvent and methanol were studied in the full composition range as a function of temperature. Thermophysical properties were measured and combined with the derived excess and mixing properties and were analysed in terms of intermolecular interactions. A vibrational spectroscopy study provided further details into hydrogen bonding changes upon mixing. The proposed mixed system allows the control and fine tuning of the properties of the deep eutectic solvent, maintaining its features but leading to suitable thermophysical properties for large scale applications. (C) 2018 Elsevier B.V. All rights reserved.
引用
收藏
页码：815 / 820
页数：6
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