Kinetics Investigation of Carbon Dioxide Hydrate Formation Process in a New Impinging Stream Reactor

The absorption of carbon dioxide by hydrates is considered as one of the potential methods for carbon capture and storage. In this work, a new impinging stream reactor was designed to investigate the characteristics of carbon dioxide hydrate formation process. The experiments were carried out at different pressure, temperature and impinging strength. It was shown that the carbon dioxide hydrate formation process could be enhanced by the impinging stream technique. With the increased of impinging strength, both gas consumption and hydration rate were increased. In addition, initial pressure and temperature also had an effect on the carbon dioxide hydrate formation process. Moreover, the kinetics of carbon dioxide hydrate formation was discussed. When the initial pressure was 3.5 MPa and impinging strength was 0.21, the activation energy was 24.74 kJ/mol, which was similar to the experimental data available in the literature.