Nanomagnetically modified ferric hydrogen sulfate (NiFe2O4@SiO2-FHS): a reusable green catalyst for the synthesis of highly functionalized piperidine derivatives

被引：35

作者：

Rahimizadeh, Mohammad ^{[1
]}

Seyedi, Seyed Mohammad ^{[1
]}

Abbasi, Mohsen ^{[1
]}

Eshghi, Hossein ^{[1
]}

Khojastehnezhad, Amir ^{[2
]}

Moeinpour, Farid ^{[3
]}

Bakavoli, Mehdi ^{[1
]}

机构：

[1] Ferdowsi Univ Mashhad, Dept Chem, Fac Sci, Mashhad, Iran

[2] Islamic Azad Univ, Mashhad Branch, Coll Sci, Dept Chem, Mashhad, Iran

[3] Islamic Azad Univ, Bandar Abbas Branch, Dept Chem, Coll Sci, Bandar Abbas 7915893144, Iran

来源：

JOURNAL OF THE IRANIAN CHEMICAL SOCIETY | 2015年 / 12卷 / 05期

关键词：

One-pot; Multi-component; Piperidine; Ferric hydrogen sulfate; Magnetically recyclable catalyst; ONE-POT SYNTHESIS; DIELS-ALDER REACTION; EFFICIENT SYNTHESIS; CONCISE SYNTHESIS; NANOPARTICLES; ACID; 5-COMPONENT; SCAFFOLDS; ATOM;

D O I：

10.1007/s13738-014-0546-z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient and one-pot multi-component procedure for the preparation of functionalized piperidine derivatives from reactions of aromatic aldehydes, substituted anilines and ethyl acetoacetate in the presence of ferric hydrogen sulfate-supported silica-coated magnetic nanoparticles (NiFe2O4@SiO2-FHS) as a magnetically recyclable green catalyst has been developed. The catalysts show environmentally benign character, which can be easily prepared, stored, and recovered several times without obvious significant loss of activity.

引用

页码：839 / 844

页数：6

共 35 条

[1] ZrCl4 as an efficient catalyst for one-pot synthesis of highly functionalized piperidines via multi-component organic reactions [J].

Aboonajmi, Jasem ;

Mousavi, Mir Rasul ;

Maghsoodlou, Malek Taher ;

Hazeri, Nourallah ;

Masoumnia, Amin .

RESEARCH ON CHEMICAL INTERMEDIATES, 2015, 41 (04) :1925-1934

[2] Nanoparticles as recyclable catalysts: The frontier between homogeneous and heterogeneous catalysis [J].

Astruc, D ;

Lu, F ;

Aranzaes, JR .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (48) :7852-7872

[3] Bismuth nitrate-catalyzed multicomponent reaction for efficient and one-pot synthesis of densely functionalized piperidine scaffolds at room temperature [J].

Brahmachari, Goutam ;

Das, Suvankar .

TETRAHEDRON LETTERS, 2012, 53 (12) :1479-1484

[4] Pot, atom and step economic (PASE) synthesis of highly functionalized piperidines: a five-component condensation [J].

Clarke, Paul A. ;

Zaytzev, Andrey V. ;

Whtwoo, Adrian C. .

TETRAHEDRON LETTERS, 2007, 48 (30) :5209-5212

[5] Intramolecular Mannich reaction in the asymmetric synthesis of polysubstituted piperidines: Concise synthesis of the dendrobate alkaloid (+)-241D and its C-4 epimer [J].

Davis, FA ;

Chao, B ;

Rao, A .

ORGANIC LETTERS, 2001, 3 (20) :3169-3171

[6] Carbon-Based Solid Acid as an Efficient and Reusable Catalyst for the Synthesis of 1,8-Dioxodecahydroacridines Under Solvent-Free Conditions [J].

Davoodnia, Abolghasem ;

Khojastehnezhad, Amir ;

Tavakoli-Hoseini, Niloofar .

BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2011, 32 (07) :2243-2248

[7] Silica supported Fe(HSO4)3 as an efficient, heterogeneous and recyclable catalyst for synthesis of β-enaminones and β-enamino esters [J].

Eshghi, Hossein ;

Seyedi, Seyed Mohammad ;

Safaei, Elham ;

Vakili, Mohammad ;

Farhadipour, Abolghasem ;

Bayat-Mokhtari, Mohtaram .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2012, 363 :430-436

[8] Synthesis of new indolyl crown ethers catalyzed with ferric hydrogensulfate [J].

Eshghi, Hossein ;

Rahimizadeh, Mohammad ;

Balchtiarpoor, Zahra ;

Pordel, Mehdi .

CHINESE CHEMICAL LETTERS, 2012, 23 (06) :673-676

[9] Catalytic asymmetric inverse-electron-demand Diels-Alder reaction of N-sulfonyl-1-aza-1,3-dienes [J].

Esquivias, Jorge ;

Gomez Arrayas, Ramon ;

Carretero, Juan C. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (06) :1480-+

[10] Enantioselective organocatalytic intramolecular aza-Michael reaction:: a concise synthesis of (+)-sedamine., (+)-allosedamine, and (+)-coniine [J].

Fustero, Santos ;

Jimenez, Diego ;

Moscardo, Javier ;

Catalan, Silvia ;

del Pozo, Carlos .

ORGANIC LETTERS, 2007, 9 (25) :5283-5286

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