Mild Hydrothermal Liquefaction of High Water Content Agricultural Residue for Bio-Crude Oil Production: A Parametric Study

被引：27
作者：
Zhang, Yongsheng [1 ,2 ]
Minaret, Jamie [2 ]
Yuan, Zhongshun [3 ]
Dutta, Animesh [2 ]
Xu, Chunbao [3 ]
机构：
[1] Zhengzhou Univ, Sch Chem Engn & Energy, 100 Sci Ave, Zhengzhou 450001, Henan, Peoples R China
[2] Univ Guelph, Sch Engn, Guelph, ON N1G 2W1, Canada
[3] Western Univ, Dept Chem & Biochem Engn, ICFAR, London, ON N6G 5B9, Canada
来源：
ENERGIES | 2018年 / 11卷 / 11期
关键词：
hydrothermal liquefaction; agricultural wastes; tomato plant wastes; bio-crude oil; BIOFUEL PRODUCTION; WOODY BIOMASS; CONVERSION; MICROALGAE; BIOREFINERIES; CELLULOSE; SPIRULINA; HTL;
D O I：
10.3390/en11113129
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
Depleting petroleum reserves together with the associated environmental concerns have intensified the exploration of alternatives to petroleum. Wet food processing wastes present promising bioresources for liquid fuel production via hydrothermal liquefaction (HTL) followed by additional upgrading. In this study, tomato plant waste (TPW) was utilized as a feedstock for the production of bio-crude oils via HTL at medium-temperature (220-280 degrees C) in water or a water-ethanol (17/3, v/v) medium in a 600 mL autoclave reactor. Effects of various operating parameters, such as catalysts (H2SO4 or KOH), reaction time (15-60 min) and reaction temperature (220-280 degrees C) on product yields were investigated. This study showed that a high yield (45.1 wt%) of bio-crude oil was achieved from HTL of TPW in water-ethanol medium at 250 degrees C in the presence of acid catalyst H2SO4. The oil, gas and solid residue (SR) products were analyzed for their chemical and structural properties.
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页数：13
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共 26 条
[1]   Hydrothermal liquefaction of the brown macro-alga Laminaria Saccharina: Effect of reaction conditions on product distribution and composition [J].
Anastasakis, K. ;
Ross, A. B. .
BIORESOURCE TECHNOLOGY, 2011, 102 (07) :4876-4883
[2]   Hydrothermal liquefaction (HTL) of microalgae for biofuel production: State of the art review and future prospects [J].
Barreiro, Diego Lopez ;
Prins, Wolter ;
Ronsse, Frederik ;
Brilman, Wim .
BIOMASS & BIOENERGY, 2013, 53 :113-127
[3]   Nutrient recycling of aqueous phase for microalgae cultivation from the hydrothermal liquefaction process [J].
Biller, P. ;
Ross, A. B. ;
Skill, S. C. ;
Lea-Langton, A. ;
Balasundaram, B. ;
Hall, C. ;
Riley, R. ;
Llewellyn, C. A. .
ALGAL RESEARCH-BIOMASS BIOFUELS AND BIOPRODUCTS, 2012, 1 (01) :70-76
[4]   Biofuels sources, biofuel policy, biofuel economy and global biofuel projections [J].
Demirbas, Ayhan .
ENERGY CONVERSION AND MANAGEMENT, 2008, 49 (08) :2106-2116
[5]   Biorefineries for biofuel upgrading: A critical review [J].
Demirbas, M. Fatih .
APPLIED ENERGY, 2009, 86 :S151-S161
[6]   Hydrothermal Liquefaction of a Microalga with Heterogeneous Catalysts [J].
Duan, Peigao ;
Savage, Phillip E. .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2011, 50 (01) :52-61
[7]   Hydrothermal liquefaction of biomass: Developments from batch to continuous process [J].
Elliott, Douglas C. ;
Biller, Patrick ;
Ross, Andrew B. ;
Schmidt, Andrew J. ;
Jones, Susanne B. .
BIORESOURCE TECHNOLOGY, 2015, 178 :147-156
[8]   Biorefineries: Current status, challenges, and future direction [J].
Fernando, Sandun ;
Adhikari, Sushil ;
Chandrapal, Chauda ;
Murali, Naveen .
ENERGY & FUELS, 2006, 20 (04) :1727-1737
[9]   Comparative Evaluation of Thermochemical Liquefaction and Pyrolysis for Bio-Oil Production from Microalgae [J].
Jena, Umakanta ;
Das, K. C. .
ENERGY & FUELS, 2011, 25 (11) :5472-5482
[10]   Thermochemical biofuel production in hydrothermal media: A review of sub- and supercritical water technologies [J].
Peterson, Andrew A. ;
Vogel, Frederic ;
Lachance, Russell P. ;
Froeling, Morgan ;
Antal, Michael J., Jr. ;
Tester, Jefferson W. .
ENERGY & ENVIRONMENTAL SCIENCE, 2008, 1 (01) :32-65
123