Ultrasound Assisted the Synthesis of 1,3-Dioxolane Derivatives from the Reaction of Epoxides or 1,2-Diols with Various Ketones Using Graphene Oxide Catalyst

被引:6
|
作者
Mirza-Aghayan, Maryam [1 ]
Mohammadi, Marzieh [1 ]
Ahmadi, Zahra [1 ]
Boukherroub, Rabah [2 ]
机构
[1] CCERCI, POB 14335-186, Tehran, Iran
[2] Univ Polytech Hauts France, Cent Lille, Univ Lille, UMR 8520,IEMN,CNRS, F-59000 Lille, France
关键词
Sonochemistry; 1,3-Dioxolane; Graphene oxide; Epoxides; 1,2-Diols; Ketone; ONE-POT SYNTHESIS; GRAPHITE OXIDE; OXIDATIVE AROMATIZATION; SULFONATED GRAPHENE; CARBONYL-COMPOUNDS; ACID CATALYST; METAL-FREE; EFFICIENT; CONVERSION; ALCOHOLS;
D O I
10.1007/s10562-020-03196-x
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The main objective of this study concerns the sonochemical synthesis of 1,3-dioxolane derivatives using graphene oxide catalyst by applying two methods. In the first method, we described the synthesis of 1,3-dioxolane by ring-opening of epoxides in the presence of ketones catalyzed by graphene oxide (GO) under ultrasonic irradiation. In the second sonochemical procedure, we described the synthesis of 1,3-dioxolane derivatives by the reaction of 1,2-diols with ketones using same GO catalyst. Mild reaction conditions, high yields, short reaction times, reusability of catalyst and easy isolation of the products make the developed methods very useful. [GRAPHICS] .
引用
收藏
页码:2959 / 2969
页数:11
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