NHC-Mediated aggregation of P4:: Isolation of a P12 cluster

被引：213

作者：

Masuda, Jason D. ^{[1
]}

Schoeller, Wolfgang W. ^{[1
]}

Donnadieu, Bruno ^{[1
]}

Bertrand, Guy ^{[1
]}

机构：

[1] Univ Calif Riverside, Dept Chem, CNRS, UMI 2957,Joint Res Chem Lab, Riverside, CA 92521 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 46期

关键词：

D O I：

10.1021/ja077296u

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Just like transition metal complexes, N-heterocyclic carbenes (NHCs) promote the aggregation of white phosphorus (P-4) as shown by the high yield synthesis of a P-12 cluster capped by two NHCs. The nuclearity observed is equal to that of the largest phosphorus cluster prepared using transition metals, but the architecture of the P-12 core is entirely novel.

引用

页码：14180 / +

页数：3