Preparation and characterization of copolymerized aminopropyl/phenylsilsesquioxane microparticles

被引：68

作者：

Liu, SM

Lang, XM

Ye, H

Zhang, SJ

Zhao, JQ ^{[1
]}

机构：

[1] S China Univ Technol, Coll Mat Sci & Engn, Guangzhou 510640, Peoples R China

[2] S China Univ Technol, Coll Chem Engn, Guangzhou 510640, Peoples R China

[3] S China Univ Technol, Key Lab GD High Property & Funct Macromol Mat, Guangzhou 510640, Peoples R China

来源：

EUROPEAN POLYMER JOURNAL | 2005年 / 41卷 / 05期

关键词：

hydrolytic co-condensation; poly(aminopropyl/phenyl)silsesquioxane; structural characterization; microparticles;

D O I：

10.1016/j.eurpolymj.2004.11.027

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(aminopropyl/phenyl)silsesquioxane (PAPSQ) microparticles with approximately 350 nm diameter were conveniently synthesized from the hydrolytic co-condensation of gamma-aminopropyltriethoxysilane (APS) and phenyltriethoxy-silane (PTES) in the presence of ethanol and water (EtOH-H2O) by using tetramethyl ammonium hydroxide (TMAOH) catalysts. Hybrid compositions of PAPSQ containing both aminopropyl and phenyl groups were confirmed from FT-IR, Si-29 CP-MAS NMR, TGA. XRD patterns indicated that a certain ordered structure existed in PAPSQ molecules. Contents of amino groups of PAPSQ were determined by elemental analysis and back titration. Specific surface areas were evaluated through BET method. PAPSQ offers the potential utility as building blocks for diverse and novel organic/inorganic materials. (c) 2004 Elsevier Ltd. All rights reserved.

引用

页码：996 / 1001

页数：6

共 27 条

[1] SILSESQUIOXANES [J].