Pore structure characteristics and fractal structure evaluation of medium- and high-rank coal

被引:28
作者
Yuan, Yuan [1 ,2 ,3 ]
Cai, Feng [1 ,3 ]
Yang, Lingling [1 ,3 ,4 ]
机构
[1] Anhui Univ Sci & Technol, State Key Lab Min Response & Disaster Prevent & C, Huainan 232001, Peoples R China
[2] Huainan Normal Univ, Sch Econ & Management, Huainan, Peoples R China
[3] Anhui Univ Sci & Technol, Sch Safety Sci & Engn, Huainan 232001, Peoples R China
[4] Hefei Technol Coll, Dept Biotechnol, Hefei, Peoples R China
关键词
Coal; pore structure characterization; fractal structure; specific surface area; adsorption and desorption; experiment of liquid nitrogen; GAS-ADSORPTION; BASIN;
D O I
10.1177/01445987211034315
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The presence of gas content in medium- and high-rank coal poses a threat to safety production. Safe gas extraction is based on a correct understanding of the pore structure of coal. This work investigates the pore structure characteristics of medium- and high-rank coal and evaluates their fractal structure. The coal samples were collected from Huainan Coalfield and Qinshui Coalfield, and divided into four types, according to the difference in surface bright characteristics. Through adopting low-temperature liquid nitrogen adsorption and desorption, and applying Kelvin equation, we obtain the main pore structure types and main pore size distribution characteristics of various coal briquettes. Electron microscope scanning structure and scientific analysis were used for special adsorption and desorption curves and hysteresis to find the dynamic reason. According to the different adsorption mechanism and Frenkel-Halsey-Hill-based model, with P/P-0 = 0.4 as the dividing point of fractal dimension analysis, the pore structure of coal samples is classified into five grades. The fractal evaluation results are consistent with the results of curve analysis and pore size analysis.
引用
收藏
页码:328 / 342
页数:15
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