Electrochemiluminescence Detection of o-aminophenol Based on PAMAM/CdSe QD/β-CD Modified Electrode

被引:0
作者
Li, Chao [1 ]
Zhang, Kun [1 ]
Liu, Fang [1 ]
Xing, Ling [1 ]
Wan, Jun [1 ]
机构
[1] Qingdao Univ Sci & Technol, Coll Environm & Safety Engn, State Key Lab Base Ecochem Engn, Qingdao, Peoples R China
来源
JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN | 2017年 / 39卷 / 04期
基金
中国国家自然科学基金;
关键词
PAMAM; CdSe QD; beta-cyclodextrin; Electrochemiluminescence (ECL); o-aminophenol; BETA-CYCLODEXTRIN; QUANTUM DOTS; PESTICIDES;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A stable and sensitive electrochemiluminescence (ECL) detection protocol of o-aminophenol was developed, which was based on CdSe quantum dots (QDs) and the cavity structure of beta-cyclodextrin. In this experiment, the working electrode was prepared by PAMAM and CdSe QD and beta-cyclodextrin using layer self-assembly method under the infrared lamp. Under the optimum conditions, a good linear relationship with the concentration of o-aminophenol from 1.0 x 10(-7) mol.L-1 to 8.0 x 10(-6) mol.L-1 and the detection limits as low as 2.3 x 10(-8) mol.L-1 (3 sigma) were achieved. Good selectivity and repeatability are advantages of the sensor which is feasible.
引用
收藏
页码:499 / 505
页数:7
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