The prospects for peroxidase-based biorefining of petroleum fuels

被引:22
作者
Ayala, Marcela [1 ]
Verdin, Jorge [1 ]
Vazquez-Duhalt, Rafael [1 ]
机构
[1] Univ Nacl Autonoma Mexico, Dept Ingn Celular & Biocatalisis, Inst Biotecnol, Cuernavaca 62250, Morelos, Mexico
关键词
petroleum biorefining; peroxidase; biocatalysis; desulfurization; biocracking; oxidative inactivation; CYTOCHROME-C PEROXIDASE; RECOMBINANT MANGANESE PEROXIDASE; REDUCTION POTENTIAL MEASUREMENTS; SITE-DIRECTED MUTAGENESIS; HORSERADISH-PEROXIDASE; LIGNIN PEROXIDASE; ESCHERICHIA-COLI; COMPOUND-I; PHANEROCHAETE-CHRYSOSPORIUM; CHEMICAL-MODIFICATION;
D O I
10.1080/10242420701379015
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Peroxidases have many potential uses for biotechnological processes. In this review, peroxidase-catalyzed reactions potentially applicable to the petroleum industry are described. Although peroxidases are attractive catalysts for desulfurization, aromatic oxidation and asphaltene transformation, there are important issues that must be overcome before any industrial application can be considered. The opportunities and challenges of enzymatic petroleum biorefining are documented and discussed, with emphasis on the available tools to design a biocatalyst with appropriate performance for the oil and other industries.
引用
收藏
页码:114 / 129
页数:16
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