Syntheses and properties of dithia-tetrahomodiaza-calix[4]arenes bridged by cystine unit

被引：1

作者：

Ito, K ^{[1
]}

Suzuki, A ^{[1
]}

Ito, N ^{[1
]}

Teraura, H ^{[1
]}

Ohba, Y ^{[1
]}

机构：

[1] Yamagata Univ, Fac Engn, Dept Chem & Chem Engn, Yonezawa, Yamagata 9928510, Japan

来源：

JOURNAL OF HETEROCYCLIC CHEMISTRY | 2003年 / 40卷 / 03期

关键词：

D O I：

10.1002/jhet.5570400302

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Dithia-tetrahomodiaza-calix[4]arenes were synthesized by the cyclization reactions of bis(3-(chloromethyl)-2-hydroxyphenyl) sulfide with cystine peptides in moderate yields. Conformational analysis of the macrocycles by using nmr spectroscopy reveled that the cyclophanes adopt a cone-like form as a preferable conformation and the cystine bridge moiety is incorporated in the cavity. The calixarene analogs can extract transion metals such as Zn2+ and Cu2+ ions from an aqueous phase into chloroform.

引用

页码：405 / 410

页数：6

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