Structuring catalyst and reactor - an inviting avenue to process intensification

被引:119
作者
Gascon, J. [1 ]
van Ommen, J. R. [1 ]
Moulijn, J. A. [1 ]
Kapteijn, F. [1 ]
机构
[1] Delft Univ Technol, NL-2628 BL Delft, Netherlands
关键词
LARGE-PORE ZEOLITE; METAL-ORGANIC FRAMEWORK; ORDERED MESOPOROUS MATERIALS; GASOLINE-RANGE HYDROCARBONS; FISCHER-TROPSCH SYNTHESIS; HEAT-TRANSFER; MONOLITHIC CATALYSTS; MIDDLE ISOPARAFFINS; TUBULAR REACTORS; GAS-LIQUID;
D O I
10.1039/c4cy01406e
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Multiphase catalytic processes involve the combination of scale-dependent and scale-independent phenomena, often resulting in a compromised, sub-optimal performance. The classical approach of randomly packed catalyst beds using unstructured catalyst particles may be outperformed by the careful design of the catalyst at the nano-scale and by the judicious choice and design of reactor. Application of structured catalysts and reactor internals and the combination of advanced reactor and catalyst systems with in situ separation allow decoupling the various phenomena involved, opening the way to intensified processes on a large scale. The integral approach of Catalysis and Reaction Engineering discussed here will play a pivotal role in the development of novel, future-proof processes.
引用
收藏
页码:807 / 817
页数:11
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