Fabrication and supercapacitive performance of long anodic TiO2 nanotube arrays using constant current anodization

被引:48
作者
Zhang, He [1 ,2 ]
Chen, Zejun [1 ,2 ]
Song, Ye [1 ]
Yin, Min [2 ]
Li, Dongdong [2 ]
Zhu, Xufei [1 ]
Chen, Xiaoyuan [2 ]
Chang, P. C. [3 ]
Lu, Linfeng [2 ]
机构
[1] Nanjing Univ Sci & Technol, Key Lab Soft Chem & Funct Mat, Educ Minist, Nanjing 210094, Jiangsu, Peoples R China
[2] Chinese Acad Sci, Shanghai Adv Res Inst, 99 Haike Rd,Zhangjiang Hitech Pk, Shanghai 201210, Peoples R China
[3] Kainan Univ, Dept Creat Ind, 1 Kainan Rd, Luchu 338, Taoyuan County, Taiwan
基金
中国国家自然科学基金;
关键词
TiO2; nanotubes; Long nanotube; Adhesion; Supercapacitor; SENSITIZED SOLAR-CELLS; LAYERS; ELECTRODES; EFFICIENCY; NANOGRASS; ANATASE; LENGTH;
D O I
10.1016/j.elecom.2016.04.004
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A galvanostatic anodization is used to prepare long TiO2 nanotube arrays (TNTAs). TNTAs of over 100 mu m in length, with similar nanotube size and structural regularity to the classic TNTAs made from potentiostatic mode, are achieved at 10 mA cm(-2). After a post-anodization in a H3PO4-based electrolyte, the TNTAs with long nanotubes exhibit good adhesion to Ti substrate. The as-prepared long TNTAs yield a larger areal capacitance of 128.4 mF cm(-2). Further, the long TNTAs possess a higher surface area, making them suitable as support templates for other active materials. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:23 / 27
页数:5
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