N-acylation: an effective method for reducing the LUMO energy levels of conjugated polymers containing five-membered lactam units

被引：69

作者：

Deng, Ping ^{[1
]}

Liu, Lu ^{[2
]}

Ren, Shendong ^{[2
]}

Li, Hongxiang ^{[2
]}

Zhang, Qing ^{[1
]}

机构：

[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, Dept Polymer Sci & Engn, Shanghai 200240, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 55期

基金：

中国国家自然科学基金;

关键词：

FIELD-EFFECT TRANSISTORS; THIN-FILM TRANSISTORS; SOLAR-CELL APPLICATIONS; HIGH-PERFORMANCE; HIGH-MOBILITY; DIIMIDE SEMICONDUCTORS; ORGANIC SEMICONDUCTORS; MATERIALS DESIGN; ACCEPTOR; NAPHTHALENE;

D O I：

10.1039/c2cc32184j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

N-acylation was studied as a method for reducing the LUMO energy levels of benzodipyrrolidone-based polymers. The N-acylated polymers showed reduced LUMO levels and improved reversibility of reductive doping compared with N-alkylated polymers. This method may also apply in other conjugated polymers with lactam repeating units.

引用

页码：6960 / 6962

页数：3

共 51 条

[1] Donor-acceptor type low band gap polymers: polysquaraines and related systems [J].

Ajayaghosh, A .

CHEMICAL SOCIETY REVIEWS, 2003, 32 (04) :181-191

[2] Spray-Processable Blue-to-Highly Transmissive Switching Polymer Electrochromes via the Donor-Acceptor Approach [J].

Amb, Chad M. ;

Beaujuge, Pierre M. ;

Reynolds, John R. .

ADVANCED MATERIALS, 2010, 22 (06) :724-+

[3] n-Type Organic Semiconductors in Organic Electronics [J].

Anthony, John E. ;

Facchetti, Antonio ;

Heeney, Martin ;

Marder, Seth R. ;

Zhan, Xiaowei .

ADVANCED MATERIALS, 2010, 22 (34) :3876-3892

[4] Molecular Design and Ordering Effects in π-Functional Materials for Transistor and Solar Cell Applications [J].

Beaujuge, Pierre M. ;

Frechet, Jean M. J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (50) :20009-20029

[5] Spectral Engineering in π-Conjugated Polymers with Intramolecular Donor-Acceptor Interactions [J].

Beaujuge, Pierre M. ;

Amb, Chad M. ;

Reynolds, John R. .

ACCOUNTS OF CHEMICAL RESEARCH, 2010, 43 (11) :1396-1407

[6] Naphthalenedicarboximide- vs Perylenedicarboximide-Based Copolymers. Synthesis and Semiconducting Properties in Bottom-Gate N-Channel Organic Transistors [J].

Chen, Zhihua ;

Zheng, Yan ;

Yan, He ;

Facchetti, Antonio .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (01) :8-+

[7] Benzodipyrrolidones and Their Polymers [J].

Cui, Weibin ;

Yuen, Jonathan ;

Wudl, Fred .

MACROMOLECULES, 2011, 44 (20) :7869-7873

[8] Naphthoylene(trifluoromethylbenzimidazole)-dicarboxylic acid imides for high-performance n-type organic field-effect transistors [J].

Deng, Ping ;

Yan, Yan ;

Wang, Sui-Dong ;

Zhang, Qing .

CHEMICAL COMMUNICATIONS, 2012, 48 (20) :2591-2593

[9] Organic photoresponse materials and devices [J].

Dong, Huanli ;

Zhu, Hongfei ;

Meng, Qing ;

Gong, Xiong ;

Hu, Wenping .

CHEMICAL SOCIETY REVIEWS, 2012, 41 (05) :1754-1808

[10] High performance organic semiconductors for field-effect transistors [J].

Dong, Huanli ;

Wang, Chengliang ;

Hu, Wenping .

CHEMICAL COMMUNICATIONS, 2010, 46 (29) :5211-5222

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