The effects of crystal structure on optical absorption/photoluminescence of bis(8-hydroxyquinoline)zinc

被引：43
作者：
Xu, BS
Hao, YY [1 ]
Wang, H
Zhou, HF
Liu, XG
Chen, MW
机构：
[1] Taiyuan Univ Technol, Coll Sci, Taiyuan 030024, Shanxi, Peoples R China
[2] Taiyuan Univ Technol, Coll Mat Sci & Engn, Taiyuan 030024, Shanxi, Peoples R China
[3] Taiyuan Univ Technol, Coll Chem Engn & Technol, Taiyuan 030024, Shanxi, Peoples R China
[4] Tohoku Univ, Inst Mat Res, Sendai, Miyagi 9808577, Japan
来源：
SOLID STATE COMMUNICATIONS | 2005年 / 136卷 / 06期
基金：
中国国家自然科学基金;
关键词：
bis(8-hydroxyquinoline)zinc; crystal structure; optical absorption; photoluminescence;
D O I：
10.1016/j.ssc.2005.08.021
中图分类号：
O469 [凝聚态物理学];
学科分类号：
070205 ;
摘要：
In this paper, the trans formal ion processes of two types of bis(8-hydroxyquinoline)zinc: Znq(2) dihydrate and anhydrous (Znq2)4 were investigated by X-ray diffraction (XRD), infrared spectra (IR), scanning electron microscope (SEM), differential scanning calorimetry (DSC) and thermogravimetry (TG). The effects of crystal structure on optical properties of bis(8-hydroxyquinoiline)zinc were analyzed. Znq(2) dihydrate can be transformed into anhydrous (Znq(2))(4) during heating under vacuum. Reversal transformation occurs by the interaction between chloroform and (Znq(2))(4). But (Znq(2))(4) was partially transformed into Znq(2) dihydrate by the interaction between ethanol and (Znq(2))(4). The different molecular structure results in different crystal stacking and electronic structure, thereby affect its optical properties. (C) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码：318 / 322
页数：5
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