A Non-interpenetrated Microporous Bi-pillared-Layer Framework: Synthesis, Structure and Photoluminescence Properties

被引：0

作者：

Lu, Jitao ^{[1
]}

Sui, Haiyan ^{[1
]}

Meng, Dandan ^{[1
]}

Meng, Qingguo ^{[1
]}

机构：

[1] Weifang Univ, Coll Chem Engn & Environm Chem, Weifang 261061, Peoples R China

来源：

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2015年 / 25卷 / 04期

关键词：

5-Hydroxyisophthalic acid; Microporous; Bi-pillared-layer; MOFs; Photoluminescence; METAL-ORGANIC FRAMEWORK; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; GAS-SORPTION; ANTITUMOR-ACTIVITY; HYDROGEN STORAGE; LIGAND; DESIGN; ADSORPTION; COMPLEXES;

D O I：

10.1007/s10904-015-0194-5

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A non-interpenetrated microporous bi-pillared-layer framework of Zn(II), {[Zn(hip)(4,4'-bipy)](DMA)center dot(4H(2)O)}(n) (1) (H(2)hip = 5-hydroxyisophthalic acid; 4,4'-bipy = 4,4'-bipyridine; DMA = N,N'-diethylformamide) composed of mixed ligand system has been synthesized and structurally characterized. The hip linkers form a 2D corrugated sheet of {Zn(hip)}(n) by linking the secondary building unit of Zn-2(CO2)(2) in the bc plane, which are further connected by double 4,4'-bipy pillars resulting in a bi-pillared-layer type 3D framework. The 3D framework is non-interpenetrated and exhibits a 3D channel structure occupied by the guest DMA molecules. The thermal stability and luminescent properties were also investigated.

引用

页码：936 / 941

页数：6

共 42 条

[1] A Non-interpenetrated Microporous Bi-pillared-Layer Framework: Synthesis, Structure and Photoluminescence Properties
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