Dissolution of uranium dioxide in supercritical fluid carbon dioxide

被引：51

作者：

Samsonov, MD

Wai, CM ^{[1
]}

Lee, SC

Kulyako, Y

Smart, NG

机构：

[1] Univ Idaho, Dept Chem, Moscow, ID 83844 USA

[2] Russian Acad Sci, VI Vernadskii Inst Geochem & Analyt Chem, Lab Radiochem, Moscow 117975, Russia

[3] BNFL, Chem Proc Grp, Sellafield CA20 1PG, Cumbria, England

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 18期

关键词：

D O I：

10.1039/b103468p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Uranium dioxide can be dissolved in supercritical CO2 with a CO2-philic TBP-HNO3 complexant to form a highly soluble UO2(NO3)(2). 2TBP complex; this new method of dissolving UO2 that requires no water or organic solvent may have important applications for reprocessing of spent nuclear fuels and for treatment of nuclear wastes.

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页码：1868 / 1869

页数：2

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