Mixed-valent diruthenium diphosphonate with kagome structure

被引：50
|
作者：
Liu, B [1 ]
Li, YZ [1 ]
Zheng, LM [1 ]
机构：
[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
来源：
INORGANIC CHEMISTRY | 2005年 / 44卷 / 20期
关键词：
D O I：
10.1021/ic050821a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This paper reports the first example of diruthenium phosphonate with kagome structure, namely, [NH3(CH2)(4)NH3][Ru-2(hedpH(0.5))(2)]center dot 2H(2)O (hedp = 1-hydroxyethylidenediphosphonate). The compound contains kagome layers that are linked by very strong hydrogen bonds into a nanoscale kagome structure. Ferromagnetic interactions are mediated between the paramagnetic diruthenium units.
引用
收藏
页码：6921 / 6923
页数：3
相关论文
共 50 条
  • [31] Redox-Induced Hydrogen Bond Reorientation Mimicking Electronic Coupling in Mixed-Valent Diruthenium and Macrocyclic Tetraruthenium Complexes
    Fink, Daniel
    Staiger, Anne
    Orth, Nicole
    Linseis, Michael
    Ivanovic-Burmazovic, Ivana
    Winter, Rainer F.
    INORGANIC CHEMISTRY, 2020, 59 (22) : 16703 - 16715
  • [32] Syntheses, structures, and magnetic properties of mixed-valent diruthenium(II,III) diphosphonates with discrete and one-dimensional structures
    Yi, XY
    Liu, B
    Jiménez-Aparicio, R
    Urbanos, FA
    Gao, S
    Xu, W
    Chen, JS
    Song, Y
    Zheng, LM
    INORGANIC CHEMISTRY, 2005, 44 (12) : 4309 - 4314
  • [33] Exploration of Vanadium(IV)-Based Single-Ion Magnet Properties in Diphosphonate-Supported Mixed-Valent Polyoxovanadates
    Singh, Pragyansh
    Schlittenhardt, Soeren
    Thakre, Dewendra
    Kushvaha, Saroj Kumar
    Kumar, Sunil
    Karnamkkott, Harsha S.
    Ruben, Mario
    Ibrahim, Masooma
    Banerjee, Abhishek
    Mondal, Kartik Chandra
    CRYSTAL GROWTH & DESIGN, 2022, 22 (09) : 5666 - 5679
  • [34] Na3Ru2(hedp)2•4H2O:: A mixed valent diruthenium diphosphonate with three-dimensional structure
    Liu, Bin
    Li, Yi-Zhi
    Zheng, Li-Min
    SOLID STATE SCIENCES, 2006, 8 (09) : 1041 - 1045
  • [35] CERHIN - A NEW MIXED-VALENT CERIUM COMPOUND
    ADROJA, DT
    MALIK, SK
    PADALIA, BD
    VIJAYARAGHAVAN, R
    PHYSICAL REVIEW B, 1989, 39 (07): : 4831 - 4833
  • [36] LATTICE-DYNAMICS OF MIXED-VALENT SMS
    MOOK, HA
    MCWHAN, DB
    HOLTZBERG, F
    PHYSICAL REVIEW B, 1982, 25 (06): : 4321 - 4323
  • [37] YbCu0.52(2)Sb: Mixed-valent compound with a layered structure
    Liu, Qian
    Liu, Xiao-Cun
    Liu, Ke-Feng
    Zhang, Jian
    Xia, Sheng-Qing
    JOURNAL OF ALLOYS AND COMPOUNDS, 2020, 847
  • [38] Attractive route to mixed-valent metal oxides
    Bernstein, S.N.
    Dunbar, K.R.
    Angewandte Chemie (International Edition in English), 1992, 31 (10):
  • [39] Class I mixed-valent dirhenium complexes
    Yan, Yong
    Mague, Joel
    Donahue, Jim
    Sproules, Stephen
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 250
  • [40] Electrostatic interactions within mixed-valent compounds
    Hildebrandt, Alexander
    Miesel, Dominique
    Lang, Heinrich
    COORDINATION CHEMISTRY REVIEWS, 2018, 371 : 56 - 66
12345