Mixed-valent diruthenium diphosphonate with kagome structure

被引：50
|
作者：
Liu, B [1 ]
Li, YZ [1 ]
Zheng, LM [1 ]
机构：
[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
来源：
INORGANIC CHEMISTRY | 2005年 / 44卷 / 20期
关键词：
D O I：
10.1021/ic050821a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This paper reports the first example of diruthenium phosphonate with kagome structure, namely, [NH3(CH2)(4)NH3][Ru-2(hedpH(0.5))(2)]center dot 2H(2)O (hedp = 1-hydroxyethylidenediphosphonate). The compound contains kagome layers that are linked by very strong hydrogen bonds into a nanoscale kagome structure. Ferromagnetic interactions are mediated between the paramagnetic diruthenium units.
引用
收藏
页码：6921 / 6923
页数：3
相关论文
共 50 条
  • [21] Amine-templated one-dimensional metal sulfates including a mixed-valent Fe compound with a half-kagome structure
    Behera, J. N.
    Rao, C. N. R.
    CHEMISTRY-AN ASIAN JOURNAL, 2006, 1 (05) : 742 - 750
  • [22] BAND CALCULATIONS FOR MIXED-VALENT SYSTEMS
    NORMAN, MR
    KOELLING, DD
    JOURNAL OF THE LESS-COMMON METALS, 1987, 127 : 357 - 366
  • [23] REDOX CONDUCTION IN MIXED-VALENT POLYMERS
    PICKUP, PG
    MURRAY, RW
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (14) : 4510 - 4514
  • [24] DIELECTRIC RESPONSE OF MIXED-VALENT TMSE
    BATLOGG, B
    PHYSICAL REVIEW B, 1981, 23 (04) : 1827 - 1838
  • [25] DYNAMIC SUSCEPTIBILITY OF MIXED-VALENT SYSTEMS
    DECHATEL, PF
    BULLETIN OF THE AMERICAN PHYSICAL SOCIETY, 1980, 25 (03): : 342 - 342
  • [26] Mixed-Valent Molecular Triple Deckers
    Schmidt, Hauke C.
    Guo, Xingwei
    Richard, Pascal U.
    Neuburger, Markus
    Palivan, Cornelia G.
    Wenger, Oliver S.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57 (36) : 11688 - 11691
  • [27] LATTICE DISTORTION IN MIXED-VALENT MATERIALS
    BABA, K
    KURODA, Y
    SOLID STATE COMMUNICATIONS, 1981, 39 (05) : 671 - 673
  • [28] MIXED-VALENT SYSTEMS AS FERMI LIQUIDS
    DECHATEL, PF
    SOLID STATE COMMUNICATIONS, 1982, 41 (11) : 853 - 855
  • [29] EXCITATION SPECTRUM OF MIXED-VALENT MATERIALS
    ICHINOSE, S
    TAMURA, I
    JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1983, 31-4 (FEB) : 459 - 460
  • [30] On the structure of a proposed mixed-valent analogue of the diiron subsite of [FeFe]-hydrogenase
    Best, Stephen P.
    Borg, Stacey J.
    White, Jonathan M.
    Razavet, Mathieu
    Pickett, Christopher J.
    CHEMICAL COMMUNICATIONS, 2007, (42) : 4348 - 4350
12345