Mixed-valent diruthenium diphosphonate with kagome structure

被引：50
|
作者：
Liu, B [1 ]
Li, YZ [1 ]
Zheng, LM [1 ]
机构：
[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
来源：
INORGANIC CHEMISTRY | 2005年 / 44卷 / 20期
关键词：
D O I：
10.1021/ic050821a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This paper reports the first example of diruthenium phosphonate with kagome structure, namely, [NH3(CH2)(4)NH3][Ru-2(hedpH(0.5))(2)]center dot 2H(2)O (hedp = 1-hydroxyethylidenediphosphonate). The compound contains kagome layers that are linked by very strong hydrogen bonds into a nanoscale kagome structure. Ferromagnetic interactions are mediated between the paramagnetic diruthenium units.
引用
收藏
页码：6921 / 6923
页数：3
相关论文
共 50 条
  • [11] Thermal decomposition of mixed-valent diruthenium pentakis(alkanoates) enhanced by their liquid crystalline state
    Rusjan, MC
    Sileo, EE
    Cukiernik, FD
    SOLID STATE IONICS, 1999, 124 (1-2) : 143 - 147
  • [12] Synthesis, structure, and bonding of a mixed-valent tetraphosphete
    Frank, Walter
    Petry, Volker
    Gerwalin, Elmar
    Reiss, Guido J.
    Angewandte Chemie (International Edition in English), 1996, 35 (13-14): : 1512 - 1514
  • [13] Synthesis, structure, and bonding of a mixed-valent tetraphosphete
    Frank, W
    Petry, V
    Gerwalin, E
    Reiss, GJ
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1996, 35 (13-14) : 1512 - 1514
  • [14] Supramolecular architecture elucidation of the room temperature columnar mesophases exhibited by mixed-valent diruthenium alkoxybenzoates
    Chaia, Zulema D.
    Rusjan, Marcia C.
    Ana Castro, Maria
    Donnio, Bertrand
    Heinrich, Benoit
    Guillon, Daniel
    Baggio, Ricardo F.
    Cukiernik, Fabio D.
    JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (28) : 4981 - 4991
  • [15] Mixed-valent diruthenium long-chain carboxylates. 2. Magnetic properties
    Cukiernik, FD
    Luneau, D
    Marchon, JC
    Maldivi, P
    INORGANIC CHEMISTRY, 1998, 37 (15) : 3698 - 3704
  • [16] Mixed-valent diruthenium (II,III) aliphatic carboxylates: columnar mesophases in dodecylsulfate and octylsulfonate derivatives
    Chaia, Z
    Zelcer, A
    Donnio, B
    Rusjan, M
    Cukiernik, FD
    Guillon, D
    LIQUID CRYSTALS, 2004, 31 (07) : 1019 - 1025
  • [17] Thermotropic mesomorphism of mixed-valent diruthenium aliphatic carboxylates with axial anion bearing two aliphatic chains
    Bottazzi, Tamara
    Cecchi, Florencia
    Zelcer, Andres
    Heinrich, Benoit
    Donnio, Bertrand
    Guillon, Daniel
    Cukiernik, Fabio D.
    JOURNAL OF COORDINATION CHEMISTRY, 2013, 66 (19) : 3380 - 3390
  • [18] Organically templated mixed-valent iron sulfates possessing Kagome and other types of layered networks
    Paul, G
    Choudhury, A
    Sampathkumaran, EV
    Rao, CNR
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2002, 41 (22) : 4297 - 4300
  • [19] THEORY OF A MIXED-VALENT IMPURITY
    RAMAKRISHNAN, TV
    SUR, K
    PHYSICAL REVIEW B, 1982, 26 (04): : 1798 - 1811
  • [20] STRUCTURE AND ANTIFERROMAGNETIC PROPERTIES OF A MIXED-VALENT MOLYBDENO MONOPHOSPHATE OF LITHIUM
    HOAREAU, T
    BOREL, MM
    LECLAIRE, A
    PROVOST, J
    RAVEAU, B
    MATERIALS RESEARCH BULLETIN, 1995, 30 (04) : 523 - 529
12345