trans-C-glycosides from 8-oxabicyclo[3.2.1]oct-6-en-3-one -: Synthesis of the C3-C13 segment of the phorboxazoles A and B

被引：57

作者：

Wolbers, P ^{[1
]}

Hoffmann, HMR ^{[1
]}

机构：

[1] Leibniz Univ Hannover, Inst Organ Chem, D-30167 Hannover, Germany

来源：

TETRAHEDRON | 1999年 / 55卷 / 07期

关键词：

D O I：

10.1016/S0040-4020(98)01196-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The enantiopure and fully resolved C3-C13 segment of the phorboxazoles A and B has been prepared in 14 steps in 24% overall yield starting from 8-oxabicyclo[3.2.1]oct-6-en-3-one. Key steps are the desymmetrization of the oxabicyclic ketone, the anomeric allylation and the asymmetric allylboration. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.

引用

页码：1905 / 1914

页数：10

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