Amphiphilic gradient copolymer of [poly(ethylene glycol) methyl ether] methacrylate and styrene via atom transfer radical polymerization

被引：17
|
作者：
Kim, Bong-Soo [1 ]
Lee, Hyo-Kyoung [1 ]
Jeong, Somi [1 ]
Lee, Jang-Oo [1 ]
Paik, Hyun-jong [1 ]
机构：
[1] Pusan Natl Univ, Dept Polymer Sci & Engn, Pusan 609735, South Korea
来源：
MACROMOLECULAR RESEARCH | 2011年 / 19卷 / 12期
基金：
新加坡国家研究基金会;
关键词：
PEGMA; atom transfer radical polymerization; styrene; amphiphilic gradient copolymer; lower critical solution temperature; GLASS-TRANSITION TEMPERATURE; GRAFT-COPOLYMERS; STRUCTURAL CONTROL; REACTIVITY RATIOS; BLOCK-COPOLYMERS; SEQUENCE DISTRIBUTION; INTERFACIAL ACTIVITY; DIBLOCK COPOLYMERS; MOLECULAR-WEIGHT; BEHAVIOR;
D O I：
10.1007/s13233-011-1207-z
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Well-defined amphiphilic gradient copolymers of poly(ethylene glycol) methyl ether methacrylate (PEGMA) and styrene were successfully synthesized using atom transfer radical polymerization. The relative reactivity ratio of PEGMA to styrene was determined using the Jaacks method. The initial feed ratio of the two monomers had a significant effect on the copolymer's gradient composition. The resultant copolymers were characterized by nuclear magnetic resonance and Fourier transform-infrared spectroscopy to confirm their structures and monomer compositions. The lower critical solution temperature behavior of the copolymers was investigated using ultravioletvisual spectroscopy. The micellization behavior of the PEGMA and styrene copolymers in aqueous solution was observed by transmission electron microscopy and dynamic laser scattering.
引用
收藏
页码：1257 / 1263
页数：7
相关论文
共 50 条
  • [31] Emulsion copolymerization of styrene and poly(ethylene glycol) ethyl ether methacrylate
    Tuncel, A
    POLYMER, 2000, 41 (04) : 1257 - 1267
  • [32] Synthesis of Poly(methyl methacrylate)-b-poly(N-isopropylacrylamide) Block Copolymer by Redox Polymerization and Atom Transfer Radical Polymerization
    Goktas, Melahat
    Deng, Guodong
    INDONESIAN JOURNAL OF CHEMISTRY, 2018, 18 (03) : 537 - 543
  • [33] Atom transfer radical polymerization of styrene and methyl methacrylate catalyzed by FeCl2/iminodiacetic acid
    Zhu, SM
    Yan, DY
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2000, 38 (23) : 4308 - 4314
  • [34] Atom Transfer Radical Polymerization of Styrene and Methyl (Meth)acrylates Initiated with Poly(dimethylsiloxane) Macroinitiator: Synthesis and Characterization of Triblock Copolymers
    Semsarzadeh, Mohammad Ali
    Abdollahi, Mahdi
    JOURNAL OF APPLIED POLYMER SCIENCE, 2012, 123 (04) : 2423 - 2430
  • [35] Chloro-telechelic poly(ethylene oxide)s as initiators for the atom transfer radical polymerization (ATRP) of styrene and methyl methacrylate -: Structural features that affect the initiation efficiency
    Reining, B
    Keul, H
    Höcker, H
    POLYMER, 1999, 40 (12) : 3555 - 3563
  • [36] Synthesis of amphiphilic block copolymer poly (styrene-b-acrylic acid) by atom transfer radical polymerization and its micellization
    Zhu, H
    Liu, SY
    Pan, QM
    Duan, HW
    Jiang, M
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2002, 23 (01): : 138 - 142
  • [37] Atom transfer radical suspension polymerization of methyl methacrylate
    Zhu, CY
    Zhao, FK
    Xia, QY
    Cao, YR
    Huang, JX
    ACTA POLYMERICA SINICA, 2001, (06) : 726 - 729
  • [38] Emulsion copolymerization of vinyl chloride with poly (ethylene glycol) methyl ether methacrylate
    Jia, Ye
    Fan, Lijun
    Song, Changtong
    Chen, Dong
    Zhang, Xianhong
    Ma, Yuhong
    Yang, Wantai
    DESIGNED MONOMERS AND POLYMERS, 2023, 26 (01) : 245 - 257
  • [39] Synthesis of poly(ethylene oxide)-block-poly(methyl methacrylate)-block-poly styrene triblock copolymers by two-step atom transfer radical polymerization
    Sun, XY
    Zhang, HL
    Huang, XH
    Wang, XY
    Zhou, QF
    POLYMER, 2005, 46 (14) : 5251 - 5257
  • [40] Synthesis of Poly(poly(ethylene glycol)methacrylate)-Polyisobutylene ABA Block Copolymers by the Combination of Quasiliving Carbocationic and Atom Transfer Radical Polymerizations
    Szabo, Akos
    Szarka, Gyoergyi
    Ivan, Bela
    MACROMOLECULAR RAPID COMMUNICATIONS, 2015, 36 (02) : 238 - 248
12345