First Example of a Heptazine-Porphyrin Dyad; Synthesis and Spectroscopic Properties

被引：1

作者：

Bregier, Frederique ^{[1
]}

Sol, Vincent ^{[1
]}

Champavier, Yves ^{[1
,2
]}

Galmiche, Laurent ^{[3
,4
]}

Allain, Clemence ^{[3
,4
]}

Audebert, Pierre ^{[3
,4
,5
]}

机构：

[1] Univ Limoges, Lab PEIRENE UR 22722, F-87000 Limoges, France

[2] Ctr Biol & Rech Sante CBRS, NMR Platform, BISCEm, F-87000 Limoges, France

[3] PPSM, Av Sci, F-91100 Gif S Yvette, France

[4] CNRS UMR 8531, 61 Ave President Wilson, F-94235 Cachan, France

[5] XLIM, UMR CNRS 7252, 123 Ave Albert Thomas, F-87060 Limoges, France

来源：

MOLECULES | 2022年 / 27卷 / 19期

关键词：

Heptazines; Porphyrins; Dyad; Photochemistry; Electrochemistry; DONOR-ACCEPTOR DYAD; BUILDING-BLOCKS; S-HEPTAZINES; MOLECULES; DYNAMICS; CATALYST; STATE;

D O I：

10.3390/molecules27196698

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

We have prepared the first example of a porphyrin linked to an heptazine photoactive antenna. The two entities, linked with an alkyl spacer, demonstrate the activity of both active moieties. While they behave electrochemically independantly, on the other hand the spectroscopy shows the existence of energy transfer between both partners.

引用

页数：6

共 25 条

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