Very Large, Soluble Endohedral Fullerenes in the Series La2C90 to La2C138: Isolation and Crystallographic Characterization of La2@D5(450)-C100

被引:64
作者
Beavers, Christine M. [2 ]
Jin, Hongxiao [1 ]
Yang, Hua [1 ]
Wang, Zhimin [1 ]
Wang, Xinqing [1 ]
Ge, Hongliang [1 ]
Liu, Ziyang [1 ]
Mercado, Brandon Q. [3 ]
Olmstead, Marilyn M. [3 ]
Balch, Alan L. [3 ]
机构
[1] China Jiliang Univ, Coll Mat Sci & Engn, Hangzhou 310027, Zhejiang, Peoples R China
[2] Univ Calif Berkeley, Lawrence Berkeley Lab, Adv Light Source, Berkeley, CA 94720 USA
[3] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA
基金
美国国家科学基金会; 中国国家自然科学基金;
关键词
HIGH-YIELD; METALLOFULLERENES; DIMETALLOFULLERENE;
D O I
10.1021/ja207090e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An extensive series of soluble dilanthanum endohedral fullerenes that extends from La2C90 to La2C138 has been discovered. The most abundant of these, the nanotubular La-2@D-5(450)-C-100, has been isolated in pure form and characterized by single-crystal X-ray diffraction.
引用
收藏
页码:15338 / 15341
页数:4
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