Immobilized vanadium amino acid Schiff base complex on Al-MCM-41 as catalyst for the epoxidation of allyl alcohols

被引：22

作者：

Zamanifar, Elham ^{[1
]}

Farzaneh, Faezeh ^{[1
]}

机构：

[1] Univ Alzahra, Dept Chem, Tehran, Iran

来源：

REACTION KINETICS MECHANISMS AND CATALYSIS | 2011年 / 104卷 / 01期

关键词：

Al-MCM-41; Vanadium complex; Epoxidation; Allyl alcohols; AROMATIC O-HYDROXYALDEHYDES; METAL-COMPLEXES; ZEOLITE-Y; OXIDATION; OXOVANADIUM(IV); STYRENE; 1,2-DIAMINOCYCLOHEXANE; COPPER(II); OXO;

D O I：

10.1007/s11144-011-0340-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Vanadium complexes of N-salicylidene-l-histidine immobilized on Al-MCM-41 designated as VO(Sal-His)/Al-MCM-41, were prepared and characterized by X-ray powder diffraction (XRD), FT-IR, nitrogen adsorption-desorption and chemical analysis techniques. VO(Sal-His)/Al-MCM-41 was found to catalyze the epoxidation of trans-2-hexen-1-ol, cinnamyl alcohol and geraniol with tert-butyl hydroperoxide (TBHP). The successful catalytic behavior of VO(Sal-His)/Al-MCM-41 with 99% conversion and excellent selectivity toward the corresponding epoxides is described herein.

引用

页码：197 / 209

页数：13

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