Immobilized vanadium amino acid Schiff base complex on Al-MCM-41 as catalyst for the epoxidation of allyl alcohols

被引：22
|
作者：
Zamanifar, Elham [1 ]
Farzaneh, Faezeh [1 ]
机构：
[1] Univ Alzahra, Dept Chem, Tehran, Iran
来源：
REACTION KINETICS MECHANISMS AND CATALYSIS | 2011年 / 104卷 / 01期
关键词：
Al-MCM-41; Vanadium complex; Epoxidation; Allyl alcohols; AROMATIC O-HYDROXYALDEHYDES; METAL-COMPLEXES; ZEOLITE-Y; OXIDATION; OXOVANADIUM(IV); STYRENE; 1,2-DIAMINOCYCLOHEXANE; COPPER(II); OXO;
D O I：
10.1007/s11144-011-0340-1
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Vanadium complexes of N-salicylidene-l-histidine immobilized on Al-MCM-41 designated as VO(Sal-His)/Al-MCM-41, were prepared and characterized by X-ray powder diffraction (XRD), FT-IR, nitrogen adsorption-desorption and chemical analysis techniques. VO(Sal-His)/Al-MCM-41 was found to catalyze the epoxidation of trans-2-hexen-1-ol, cinnamyl alcohol and geraniol with tert-butyl hydroperoxide (TBHP). The successful catalytic behavior of VO(Sal-His)/Al-MCM-41 with 99% conversion and excellent selectivity toward the corresponding epoxides is described herein.
引用
收藏
页码：197 / 209
页数：13
相关论文
共 50 条
  • [21] Catalytic oxidation of styrene by manganese(II) bipyridine complex cations immobilized in mesoporous Al-MCM-41
    Kim, SS
    Zhang, WZ
    Pinnavaia, TJ
    CATALYSIS LETTERS, 1997, 43 (1-2) : 149 - 154
  • [22] Catalytic oxidation of styrene by manganese(II) bipyridine complex cations immobilized in mesoporous Al-MCM-41
    S.-S. Kim
    W. Zhang
    T.J. Pinnavaia
    Catalysis Letters, 1997, 43 : 149 - 154
  • [23] Asymmetric epoxidation of alkenes catalysed by chromium binaphthyl Schiff base complex supported on MCM-41
    Zhou, XG
    Yu, XQ
    Huang, JS
    Li, SG
    Li, LS
    Che, CM
    CHEMICAL COMMUNICATIONS, 1999, (18) : 1789 - 1790
  • [24] ClO4−/Al-MCM-41 nanoparticles as a solid acid catalyst for the synthesis of 2-amino-3-cyanopyridines
    Mohammad Abdollahi-Alibeik
    Neda Sadeghi-Vasafi
    Ali Moaddeli
    Ali Rezaeipoor-Anari
    Research on Chemical Intermediates, 2016, 42 : 2867 - 2881
  • [25] ClO4-/Al-MCM-41 nanoparticles as a solid acid catalyst for the synthesis of 2-amino-3-cyanopyridines
    Abdollahi-Alibeik, Mohammad
    Sadeghi-Vasafi, Neda
    Moaddeli, Ali
    Rezaeipoor-Anari, Ali
    RESEARCH ON CHEMICAL INTERMEDIATES, 2016, 42 (04) : 2867 - 2881
  • [26] Preparation of Mn (salen)/Al-MCM-41 catalyst under microwave irradiation and its catalytic performance in epoxidation of styrene
    Zhang, Y
    Yin, DH
    Fu, ZH
    Li, CZ
    Yin, DL
    CHINESE JOURNAL OF CATALYSIS, 2003, 24 (12) : 942 - 946
  • [27] Copper(II) Schiff base complex immobilized on graphene nanosheets: a heterogeneous catalyst for epoxidation of olefins
    Ali Zarnegaryan
    Zari Pahlevanneshan
    Majid Moghadam
    Shahram Tangestaninejad
    Valiollah Mirkhani
    Iraj Mohammdpoor-Baltork
    Journal of the Iranian Chemical Society, 2019, 16 : 747 - 756
  • [28] Copper(II) Schiff base complex immobilized on graphene nanosheets: a heterogeneous catalyst for epoxidation of olefins
    Zarnegaryan, Ali
    Pahlevanneshan, Zari
    Moghadam, Majid
    Tangestaninejad, Shahram
    Mirkhani, Valiollah
    Mohammdpoor-Baltork, Iraj
    JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2019, 16 (04) : 747 - 756
  • [29] Vanadium-Schiff base complex covalently bonded on modified MCM-41 as catalyst for asymmetric oxidation of methyl phenyl sulfide
    Ben Zid, T.
    Khedher, I.
    Ksibi, Z.
    Fraile, J. M.
    JOURNAL OF POROUS MATERIALS, 2016, 23 (02) : 507 - 516
  • [30] Vanadium-Schiff base complex covalently bonded on modified MCM-41 as catalyst for asymmetric oxidation of methyl phenyl sulfide
    T. Ben Zid
    I. Khedher
    Z. Ksibi
    J. M. Fraile
    Journal of Porous Materials, 2016, 23 : 507 - 516
12345