Immobilized vanadium amino acid Schiff base complex on Al-MCM-41 as catalyst for the epoxidation of allyl alcohols

被引：22

作者：

Zamanifar, Elham ^{[1
]}

Farzaneh, Faezeh ^{[1
]}

机构：

[1] Univ Alzahra, Dept Chem, Tehran, Iran

来源：

REACTION KINETICS MECHANISMS AND CATALYSIS | 2011年 / 104卷 / 01期

关键词：

Al-MCM-41; Vanadium complex; Epoxidation; Allyl alcohols; AROMATIC O-HYDROXYALDEHYDES; METAL-COMPLEXES; ZEOLITE-Y; OXIDATION; OXOVANADIUM(IV); STYRENE; 1,2-DIAMINOCYCLOHEXANE; COPPER(II); OXO;

D O I：

10.1007/s11144-011-0340-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Vanadium complexes of N-salicylidene-l-histidine immobilized on Al-MCM-41 designated as VO(Sal-His)/Al-MCM-41, were prepared and characterized by X-ray powder diffraction (XRD), FT-IR, nitrogen adsorption-desorption and chemical analysis techniques. VO(Sal-His)/Al-MCM-41 was found to catalyze the epoxidation of trans-2-hexen-1-ol, cinnamyl alcohol and geraniol with tert-butyl hydroperoxide (TBHP). The successful catalytic behavior of VO(Sal-His)/Al-MCM-41 with 99% conversion and excellent selectivity toward the corresponding epoxides is described herein.

引用

页码：197 / 209

页数：13

共 38 条

[1] Spectroscopic characterization of amino acid and amino acid ester-Schiff-base complexes of oxovanadium and their catalysis in sulfide oxidation
Ando, R
Inden, H
Sugino, M
Ono, H
Sakaeda, D
Yagyu, T
Maeda, M
[J]. INORGANICA CHIMICA ACTA, 2004, 357 (05) : 1337 - 1344
[2] Synthesis, characterization and study of vanadyl tetradentate Schiff base complexes as catalyst in aerobic selective oxidation of olefins
Boghaei, DM
Mohebi, S
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2002, 179 (1-2) : 41 - 51
[3] Transition-metal complexes for liquid-phase catalytic oxidation:: some aspects of industrial reactions and of emerging technologies
Brégeault, JM
[J]. DALTON TRANSACTIONS, 2003, (17) : 3289 - 3302
[4] Utilisation of homogeneous and supported chiral metal(salen) complexes in asymmetric catalysis
Canali, L
Sherrington, DC
[J]. CHEMICAL SOCIETY REVIEWS, 1999, 28 (02) : 85 - 93
[5] Oxo-bridged bis oxo-vanadium(V) complexes with tridentate Schiff base ligands (VOL)2O (L = SAE, SAMP, SAP): Synthesis, structure and epoxidation catalysis under solvent-free conditions
Cordelle, Cindy
Agustin, Dominique
Daran, Jean-Claude
Poli, Rinaldo
[J]. INORGANICA CHIMICA ACTA, 2010, 364 (01) : 144 - 149
[6] de Montellano P.R. Ortiz., 1995, CYTOCHROME P450 STRU
[7] Oxidation, epoxidation and sulfoxidation reactions catalysed by haloperoxidases
Dembitsky, VM
[J]. TETRAHEDRON, 2003, 59 (26) : 4701 - 4720
[8] V-MCM-41 as selective catalyst for epoxidation of olefins and trans-2-hexene-1-ol
Farzaneh, F
Zamanifar, E
Williams, CD
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2004, 218 (02) : 203 - 209
[9] Homogeneous bio-inspired copper-catalyzed oxidation reactions
Gamez, P
Aubel, PG
Driessen, WL
Reedijk, J
[J]. CHEMICAL SOCIETY REVIEWS, 2001, 30 (06) : 376 - 385
[10] Catalytic activities of Schiff base transition metal complexes
Gupta, K. C.
Sutar, Alekha Kumar
[J]. COORDINATION CHEMISTRY REVIEWS, 2008, 252 (12-14) : 1420 - 1450

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