Immobilized vanadium amino acid Schiff base complex on Al-MCM-41 as catalyst for the epoxidation of allyl alcohols

被引：22
|
作者：
Zamanifar, Elham [1 ]
Farzaneh, Faezeh [1 ]
机构：
[1] Univ Alzahra, Dept Chem, Tehran, Iran
来源：
REACTION KINETICS MECHANISMS AND CATALYSIS | 2011年 / 104卷 / 01期
关键词：
Al-MCM-41; Vanadium complex; Epoxidation; Allyl alcohols; AROMATIC O-HYDROXYALDEHYDES; METAL-COMPLEXES; ZEOLITE-Y; OXIDATION; OXOVANADIUM(IV); STYRENE; 1,2-DIAMINOCYCLOHEXANE; COPPER(II); OXO;
D O I：
10.1007/s11144-011-0340-1
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Vanadium complexes of N-salicylidene-l-histidine immobilized on Al-MCM-41 designated as VO(Sal-His)/Al-MCM-41, were prepared and characterized by X-ray powder diffraction (XRD), FT-IR, nitrogen adsorption-desorption and chemical analysis techniques. VO(Sal-His)/Al-MCM-41 was found to catalyze the epoxidation of trans-2-hexen-1-ol, cinnamyl alcohol and geraniol with tert-butyl hydroperoxide (TBHP). The successful catalytic behavior of VO(Sal-His)/Al-MCM-41 with 99% conversion and excellent selectivity toward the corresponding epoxides is described herein.
引用
收藏
页码：197 / 209
页数：13
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