Characteristics of heterophase radical graft polymerization of methyl methacrylate on polymer fibres

被引：10

作者：

Bikkullova, AR ^{[1
]}

Druzhinina, TV ^{[1
]}

Abronin, IA ^{[1
]}

机构：

[1] Moscow State Tech Univ, Moscow, Russia

来源：

FIBRE CHEMISTRY | 2005年 / 37卷 / 01期

关键词：

Cellulose; Hydrated; Enthalpy; Polymer Matrix; PMMA;

D O I：

10.1007/s10692-005-0042-4

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Graft copolymers with graft PMMA were synthesized using the Cu2+-H2O2 redox system. The conditions for obtaining graft PCA-PMMA and HC-PMMA of 40-60 composite composition with grafting efficiency at the 85% level are found. The effect to the polymer matrix on the kinetic and thermodynamic properties of graft polymerization of MMA is revealed. Possible schemes of the reactions of graft polymerization of MMA to polycaproamide and hydrated cellulose are proposed based on quantum chemical calculations of the enthalpy of formation of the graft copolymers.

引用

页码：11 / 17

页数：7