Facile Synthesis of Carbon-Encapsulated Ni Nanoparticles Embedded into Porous Graphite Sheets as High-Performance Microwave Absorber

被引:20
作者
Du, Xia
Wang, Bochong [1 ]
Mu, Congpu
Wen, Fusheng [1 ]
Xiang, Jianyong
Nie, Anmin
Liu, Zhongyuan [1 ]
机构
[1] Yanshan Univ, State Key Lab Metastable Mat Sci & Technol, Qinhuangdao 066004, Peoples R China
基金
中国国家自然科学基金;
关键词
Nickel particles; Porous carbon; Reflection loss; Microwave absorption; Quarter-wavelength matching model; ELECTROMAGNETIC-WAVE ABSORPTION; LIGHTWEIGHT; ENHANCEMENT; FABRICATION; NANOSPHERES; NANOSHEETS;
D O I
10.1021/acssuschemeng.8b02944
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The Ni@C nanohybrids were prepared by a unique and efficient method of annealing the organic carbon compound and metal nitrate. Morphology detection demonstrated the Ni nanoparticles were uniformly encapsulated into the carbon network. The microwave absorption of 10 wt % Ni@C nanohybrids with paraffin matrix was measured over the range of 1-18 GHz. The complex permittivity was adjusted by changing the carbon proportions because of the superior conductivity of graphite. The minimum reflection loss (RL) value of -56 dB was obtained at 15.8 GHz with a thickness of 1.8 mm and the effective absorption bandwidth (RL <= -10 dB) was 5.4 GHz. Therefore, the Ni@C nanohybrids have great potential to be utilized as a high-efficiency and lightweight microwave absorber.
引用
收藏
页码:16179 / 16185
页数:13
相关论文
共 42 条
[31]   Fabrication of carbon encapsulated Co3O4 nanoparticles embedded in porous graphitic carbon nanosheets for microwave absorber [J].
Wen, Fusheng ;
Hou, Hang ;
Xiang, Jianyong ;
Zhang, Xiaoyan ;
Su, Zhibin ;
Yuan, Shijun ;
Liu, Zhongyuan .
CARBON, 2015, 89 :372-377
[32]   Co2+/Co3+ ratio dependence of electromagnetic wave absorption in hierarchical NiCo2O4-CoNiO2 hybrids [J].
Wu, Hongjing ;
Wu, Guanglei ;
Ren, Yanyan ;
Yang, Le ;
Wang, Liuding ;
Li, Xinghua .
JOURNAL OF MATERIALS CHEMISTRY C, 2015, 3 (29) :7677-7690
[33]   Magnetic carbon nanofibers containing uniformly dispersed Fe/Co/Ni nanoparticles as stable and high-performance electromagnetic wave absorbers [J].
Xiang, Jun ;
Li, Jiale ;
Zhang, Xionghui ;
Ye, Qin ;
Xu, Jiahuan ;
Shen, Xiangqian .
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (40) :16905-16914
[34]   The synergistic effects of carbon coating and micropore structure on the microwave absorption properties of Co/CoO nanoparticles [J].
Xie, Xiubo ;
Pang, Yu ;
Kikuchi, Hiroaki ;
Liu, Tong .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2016, 18 (44) :30507-30514
[35]   Fabrication of NiCo2-Anchored Graphene Nanosheets by Liquid Phase Exfoliation for Excellent Microwave Absorbers [J].
Yang, Ruilong ;
Wang, Bochong ;
Xiang, Jianyong ;
Mu, Congpu ;
Zhang, Can ;
Wen, Fusheng ;
Wang, Cong ;
Su, Can ;
Liu, Zhongyuan .
ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (14) :12673-12679
[36]   Microwave Absorption Properties of CoS2 Nanocrystals Embedded into Reduced Graphene Oxide [J].
Zhang, Can ;
Wang, Bochong ;
Xiang, Jianyong ;
Su, Can ;
Mu, Congpu ;
Wen, Fusheng ;
Liu, Zhongyuan .
ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (34) :28868-28875
[37]   Electromagnetic characteristics and microwave absorption properties of carbon-encapsulated cobalt nanoparticles in 2-18-GHz frequency range [J].
Zhang Danfeng ;
Xu Fangxing ;
Lin Jin ;
Yang Zhenda ;
Zhang Min .
CARBON, 2014, 80 :103-111
[38]   Thermal conversion of an Fe3O4@metal-organic framework: a new method for an efficient Fe-Co/nanoporous carbon microwave absorbing material [J].
Zhang, Xingmiao ;
Ji, Guangbin ;
Liu, Wei ;
Quan, Bin ;
Liang, Xiaohui ;
Shang, Chaomei ;
Cheng, Yan ;
Du, Youwei .
NANOSCALE, 2015, 7 (30) :12932-12942
[39]   Preparation of Honeycomb SnO2 Foams and Configuration-Dependent Microwave Absorption Features [J].
Zhao, Biao ;
Fan, Bingbing ;
Xu, Yawei ;
Shao, Gang ;
Wang, Xiaodong ;
Zhao, Wanyu ;
Zhang, Rui .
ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (47) :26217-26225
[40]   Lightweight hollow carbon nanospheres with tunable sizes towards enhancement in microwave absorption [J].
Zhou, Chen ;
Geng, Sai ;
Xu, Xiuwen ;
Wang, Tihong ;
Zhang, Liqiang ;
Tian, Xiaojuan ;
Yang, Fan ;
Yang, Haitao ;
Li, Yongfeng .
CARBON, 2016, 108 :234-241