Facile Synthesis of Carbon-Encapsulated Ni Nanoparticles Embedded into Porous Graphite Sheets as High-Performance Microwave Absorber

被引:20
作者
Du, Xia
Wang, Bochong [1 ]
Mu, Congpu
Wen, Fusheng [1 ]
Xiang, Jianyong
Nie, Anmin
Liu, Zhongyuan [1 ]
机构
[1] Yanshan Univ, State Key Lab Metastable Mat Sci & Technol, Qinhuangdao 066004, Peoples R China
基金
中国国家自然科学基金;
关键词
Nickel particles; Porous carbon; Reflection loss; Microwave absorption; Quarter-wavelength matching model; ELECTROMAGNETIC-WAVE ABSORPTION; LIGHTWEIGHT; ENHANCEMENT; FABRICATION; NANOSPHERES; NANOSHEETS;
D O I
10.1021/acssuschemeng.8b02944
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The Ni@C nanohybrids were prepared by a unique and efficient method of annealing the organic carbon compound and metal nitrate. Morphology detection demonstrated the Ni nanoparticles were uniformly encapsulated into the carbon network. The microwave absorption of 10 wt % Ni@C nanohybrids with paraffin matrix was measured over the range of 1-18 GHz. The complex permittivity was adjusted by changing the carbon proportions because of the superior conductivity of graphite. The minimum reflection loss (RL) value of -56 dB was obtained at 15.8 GHz with a thickness of 1.8 mm and the effective absorption bandwidth (RL <= -10 dB) was 5.4 GHz. Therefore, the Ni@C nanohybrids have great potential to be utilized as a high-efficiency and lightweight microwave absorber.
引用
收藏
页码:16179 / 16185
页数:13
相关论文
共 42 条
[1]   Thermally Driven Transport and Relaxation Switching Self-Powered Electromagnetic Energy Conversion [J].
Cao, Maosheng ;
Wang, Xixi ;
Cao, Wenqiang ;
Fang, Xiaoyong ;
Wen, Bo ;
Yuan, Jie .
SMALL, 2018, 14 (29)
[2]   The Outside-In Approach To Construct Fe3O4 Nanocrystals/Mesoporous Carbon Hollow Spheres Core-Shell Hybrids toward Microwave Absorption [J].
Cheng, Yan ;
Cao, Jieming ;
Li, Yong ;
Li, Zhaoyong ;
Zhao, Huanqin ;
Ji, Guangbin ;
Du, Youwei .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2018, 6 (01) :1427-1435
[3]   Porous-carbon-based Mo2C nanocomposites as excellent microwave absorber: a new exploration [J].
Dai, Sisi ;
Cheng, Yan ;
Quan, Bin ;
Liang, Xiaohui ;
Liu, Wei ;
Yang, Zhihong ;
Ji, Guangbin ;
Du, Youwei .
NANOSCALE, 2018, 10 (15) :6945-6953
[4]   Graphene-wrapped ZnO hollow spheres with enhanced electromagnetic wave absorption properties [J].
Han, Meikang ;
Yin, Xiaowei ;
Kong, Luo ;
Li, Mian ;
Duan, Wenyan ;
Zhang, Litong ;
Cheng, Laifei .
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (39) :16403-16409
[5]   The microwave absorption properties of carbon-encapsulated nickel nanoparticles/silicone resin flexible absorbing material [J].
Huang, Yingxin ;
Zhang, Haiyan ;
Zeng, Guoxun ;
Li, Zhenghui ;
Zhang, Danfeng ;
Zhu, Haiping ;
Xie, Runfeng ;
Zheng, Liming ;
Zhu, Jionghang .
JOURNAL OF ALLOYS AND COMPOUNDS, 2016, 682 :138-143
[6]   Effect of Pore Morphology on the Dielectric Properties of Porous Carbons for Microwave Absorption Applications [J].
Huang, Yunxia ;
Wang, Yan ;
Li, Zhimin ;
Yang, Zi ;
Shen, Chunhao ;
He, Chuangchuang .
JOURNAL OF PHYSICAL CHEMISTRY C, 2014, 118 (45) :26027-26032
[7]   Carbon-Encapsulated Fe Nanoparticles Embedded in Organic Polypyrrole Polymer as a High Performance Microwave Absorber [J].
Jiang, Linwen ;
Wang, Zhenhua ;
Geng, Dianyu ;
Wang, Yu ;
An, Jing ;
He, Jun ;
Li, Da ;
Liu, Wei ;
Zhang, Zhidong .
JOURNAL OF PHYSICAL CHEMISTRY C, 2016, 120 (49) :28320-28329
[8]   Sodium alginate-based magnetic carbonaceous biosorbents for highly efficient Cr(VI) removal from water [J].
Lei, Zhimin ;
Zhai, Shangru ;
Lv, Jialiang ;
Fan, Yuan ;
An, Qingda ;
Xiao, Zuoyi .
RSC ADVANCES, 2015, 5 (95) :77932-77941
[9]   Microporous Co@C Nanoparticles Prepared by Dealloying CoAl@C Precursors: Achieving Strong Wideband Microwave Absorption via Controlling Carbon Shell Thickness [J].
Li, Da ;
Liao, Haoyan ;
Kikuchi, Hiroaki ;
Liu, Tong .
ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (51) :44704-44714
[10]   Microwave Absorption Enhancement of Porous Carbon Fibers Compared with Carbon Nanofibers [J].
Li, Guang ;
Xie, Tianshi ;
Yang, Shenglin ;
Jin, Junhong ;
Jiang, Jianming .
JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (16) :9196-9201