Systematics of stability constants of fulvate complexes with rare earth ions

被引：32

作者：

Yamamoto, Y ^{[1
]}

Takahashi, Y

Shimizu, H

机构：

[1] Hiroshima Univ, Dept Earth & Planetary Syst Sci, Higashihiroshima 7398526, Japan

[2] Hiroshima Univ, Progect Ctr MIRAGE, Higashihiroshima 7398526, Japan

来源：

CHEMISTRY LETTERS | 2005年 / 34卷 / 06期

关键词：

D O I：

10.1246/cl.2005.880

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Stability constants of all rare earth ions (REE) with fulvic acid were determined using solvent extraction coupled with ICP-MS detection. REE pattern of the stability constant of REE fulvates shows a similar pattern to REE-carboxylate complex, suggesting that carboxylic group is the main binding site of REE in humic substances. The stability constants for all REE are indispensable for the understanding of REE patterns in natural aquifer.

引用

页码：880 / 881

页数：2

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