Removal of boron from water by electrodialysis: effect of feed characteristics and interfering ions

被引:69
作者
Kabay, N. [1 ]
Arar, O. [2 ]
Acar, F. [1 ]
Ghazal, A. [1 ]
Yuksel, U. [2 ]
Yuksel, M. [1 ]
机构
[1] Ege Univ, Dept Chem Engn, TR-35100 Izmir, Turkey
[2] Ege Univ, Dept Chem, TR-35100 Izmir, Turkey
关键词
boron; chloride; electrodialysis; specific power consumption (SPC); sulphate; water;
D O I
10.1016/j.desal.2007.01.207
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Boron removal from aqueous solution by electrodialysis was studied as a function of solution pH, applied voltage, flow rate and initial boron concentration. TS-1-10 electrodialysis equipment (Tokuyama) modified with rotameters was employed for experimental Studies. It was obtained that the highest boron transport was achieved at pH 10.5 due to the increase in dissociation of boric acid in the solution. When initial boron concentration in the solution is high, percent removal of boron increased. The existence of chloride affected the efficiency of boron removal. The effect of sulphate ions was not so apparent for boron removal although the process time for boron separation became longer in the presence of sulphate ions. It was obtained that the specific power consumption increased when the boron concentration in the solution and pH of solution was increased. SPC values increased as the number of ionic species in the solution increased.
引用
收藏
页码:63 / 72
页数:10
相关论文
共 34 条
[1]   Boron removal by ion exchange membranes [J].
Ayyildiz, HF ;
Kara, H .
DESALINATION, 2005, 180 (1-3) :99-108
[2]   Removal of boron from wastewater of geothermal power plant by selective ion-exchange resins. I. Batch sorption-elution studies [J].
Badruk, M ;
Kabay, N ;
Demircioglu, M ;
Mordogan, H ;
Ipekoglu, U .
SEPARATION SCIENCE AND TECHNOLOGY, 1999, 34 (13) :2553-2569
[3]   Modification of crosslinked glycidyl methacrylate-based polymers for boron-specific column extraction [J].
Biçak, N ;
Bulutçu, N ;
Senkal, BF ;
Gazi, M .
REACTIVE & FUNCTIONAL POLYMERS, 2001, 47 (03) :175-184
[4]   Removal of boron from aqueous solutions by continuous polymer-enhanced ultrafiltration with polyvinyl alcohol [J].
Dilek, Ç ;
Özbelge, HÖ ;
Biçak, N ;
Yilmaz, L .
SEPARATION SCIENCE AND TECHNOLOGY, 2002, 37 (06) :1257-1271
[5]   Boron removal from landfill leachate by means of nanofiltration and reverse osmosis [J].
Dydo, P ;
Turek, M ;
Ciba, J ;
Trojanowska, J ;
Kluczka, J .
DESALINATION, 2005, 185 (1-3) :131-137
[6]  
Fukunaga Koh-Ichi, 1997, Membrane, V22, P211
[7]   Removal and recovery of boron from geothermal wastewater by selective ion-exchange resins - II. Field tests [J].
Kabay, N ;
Yilmaz, I ;
Yamac, S ;
Yuksel, M ;
Yuksel, U ;
Yildirim, N ;
Aydogdu, O ;
Iwanaga, T ;
Hirowatari, K .
DESALINATION, 2004, 167 (1-3) :427-438
[8]   Removal and recovery of boron from geothermal wastewater by selective ion exchange resins. I. Laboratory tests [J].
Kabay, N ;
Yilmaz, I ;
Yamac, S ;
Samatya, S ;
Yuksel, M ;
Yuksel, U ;
Arda, M ;
Saglam, M ;
Iwanaga, T ;
Hirowatari, K .
REACTIVE & FUNCTIONAL POLYMERS, 2004, 60 :163-170
[9]   Separation of monovalent and divalent ions from ternary mixtures by electrodialysis [J].
Kabay, Nalan ;
Kahveci, Hafize ;
Ipek, Ozgur ;
Yuksel, Mithat .
DESALINATION, 2006, 198 (1-3) :74-83
[10]   Synthesis, characterization and application of a novel sorbent, glucamine-modified MCM-41, for the removal/preconcentration of boron from waters [J].
Kaftan, Ö ;
Açikel, M ;
Eroglu, AE ;
Shahwan, T ;
Artok, L ;
Ni, CY .
ANALYTICA CHIMICA ACTA, 2005, 547 (01) :31-41