Ionic Liquids: Structure and Photochemical Reactions

被引:0
作者
Castner, Edward W., Jr. [1 ]
Margulis, Claudio J. [2 ]
Maroncelli, Mark [3 ]
Wishart, James F. [4 ]
机构
[1] Rutgers State Univ, Dept Chem & Chem Biol, Piscataway, NJ 08854 USA
[2] Univ Iowa, Dept Chem, Iowa City, IA 52242 USA
[3] Penn State Univ, Dept Chem, University Pk, PA 16802 USA
[4] Brookhaven Natl Lab, Dept Chem, Upton, NY 11973 USA
来源
ANNUAL REVIEW OF PHYSICAL CHEMISTRY, VOL 62 | 2011年 / 62卷
关键词
nanostructural organization; structure factors; electron transfer; dynamic heterogeneity; distributed kinetics; ionic liquid; ELECTRON-TRANSFER REACTIONS; MOLECULAR-DYNAMICS SIMULATIONS; INTRAMOLECULAR PROTON-TRANSFER; EXCITED-STATE DYNAMICS; ROOM-TEMPERATURE; 1-BUTYL-3-METHYLIMIDAZOLIUM HEXAFLUOROPHOSPHATE; CHARGE-TRANSFER; HETEROGENEOUS DYNAMICS; PHYSICAL-CHEMISTRY; REDOX PROCESSES;
D O I
10.1146/annurev-physchem-032210-103421
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ionic liquids are subjects of intense current interest within the physical chemistry community. A great deal of progress has been made in just the past five years toward identifying the factors that cause these salts to have low melting points and other useful properties. Supramolecular structure and organization have emerged as important and complicated topics that may be key to understanding how chemical reactions and other processes are affected by ionic liquids. New questions are posed, and an active debate is ongoing regarding the nature of nanoscale ordering in ionic liquids. The topic of reactivity in ionic liquids is still relatively unexplored; however, the results that have been obtained indicate that distributed kinetics and dynamical heterogeneity may sometimes, but not always, be influencing factors.
引用
收藏
页码:85 / 105
页数:21
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