Stereumins H-J, Stereumane-Type Sesquiterpenes from the Fungus Stereum sp.

被引：33

作者：

Li, Guohong ^{[2
]}

Liu, Fangfang ^{[2
]}

Shen, Lan ^{[1
]}

Zhu, Huajie ^{[1
]}

Zhang, Keqin ^{[2
]}

机构：

[1] Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650204, Peoples R China

[2] Yunnan Univ, Key Lab Conservat & Utilizat Bioresource, Kunming 650091, Peoples R China

来源：

JOURNAL OF NATURAL PRODUCTS | 2011年 / 74卷 / 02期

关键词：

ABSOLUTE-CONFIGURATION; OPTICAL-ROTATION; NMR; IDENTIFICATION; METABOLITES; INHIBITOR; MOLECULES; PRODUCTS;

D O I：

10.1021/np100813f

中图分类号：

Q94 [植物学];

学科分类号：

071001 ;

摘要：

Stereumins H (1), I (2), and J (3), three sesquiterpenes possessing a novel stereumane-type backbone, were isolated from an extract of culture broth of the Basidiomycete Stereum sp. CCTCC AF 207024. The complete structural assignments including the absolute configurations are reported by using X-ray studies and density functional theory at the B3LYP/aug-cc-pVDZ//B3LYP/6-31G(d) level.

引用

页码：296 / 299

页数：4

共 24 条

[1] Bioactive sesquiterpenes produced by fungi: are they useful for humans as well? [J].

Abraham, WR .

CURRENT MEDICINAL CHEMISTRY, 2001, 8 (06) :583-606

[2] Conformational studies by dynamic NMR .62. Stereomutations of rotamers and of conformational enantiomers in 1,2-diacylbenzenes [J].

Casarini, D ;

Lunazzi, L ;

Mazzanti, A .

JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (22) :7592-7596

[3] Vladimuliecins A and B: Cytotoxic Pentacyclic Pregnanols from Vladimiria muliensis [J].

Chen, Jian-Jun ;

Li, Zheng-Ming ;

Gao, Kun ;

Chang, Jin ;

Yao, Xiao-Jun .

JOURNAL OF NATURAL PRODUCTS, 2009, 72 (06) :1128-1132

[4] ent-labdane diterpenoid lactone stereoisomers from Andrographis paniculata [J].

Chen, Lixia ;

Zhu, Huajie ;

Wang, Rui ;

Zhou, Kailan ;

Jing, Yongkui ;

Qiu, Feng .

JOURNAL OF NATURAL PRODUCTS, 2008, 71 (05) :852-855

[5] Configurational and conformational analysis of chiral molecules using IR and VCD spectroscopies:: Spiropentylcarboxylic acid methyl ester and spiropentyl acetate [J].

Devlin, FJ ;

Stephens, PJ ;

Österle, C ;

Wiberg, KB ;

Cheeseman, JR ;

Frisch, MJ .

JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (23) :8090-8096

[6] Naphthospironone A: An Unprecedented and Highly Functionalized Polycyclic Metabolite from an Alkaline Mine Waste Extremophile [J].

Ding, Zhang-Gui ;

Li, Ming-Gang ;

Zhao, Jiang-Yuan ;

Ren, Jie ;

Huang, Rong ;

Xie, Ming-Jin ;

Cui, Xiao-Long ;

Zhu, Hua-Jie ;

Wen, Meng-Liang .

CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (13) :3902-3905

[7]

Dodds J.L., 1980, J. Mol. Phys, V41, P1419

[8] Determination of the absolute configuration of flexible molecules by ab initio ORD calculations:: A case study with cytoxazones and isocytoxazones [J].

Giorgio, E ;

Roje, M ;

Tanaka, K ;

Hamersak, Z ;

Sunjic, V ;

Nakanishi, K ;

Rosini, C ;

Berova, N .

JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (17) :6557-6563

[9] Stereumin A-E, sesquiterpenoids from the fungus Stereum sp CCTCC AF 207024 [J].

Li, Guo-Hong ;

Duan, Meng ;

Yu, Ze-Fen ;

Li, Lei ;

Dong, Jin-Yan ;

Wang, Xing-Biao ;

Guo, Jian-Wei ;

Huang, Rong ;

Wang, Min ;

Zhang, Ke-Qin .

PHYTOCHEMISTRY, 2008, 69 (06) :1439-1445

[10] Hirsutane-Type Sesquiterpenes with Uncommon Modifications from Three Basidiomycetes [J].

Liermann, Johannes C. ;

Schueffler, Anja ;

Wollinsky, Beate ;

Birnbacher, Judith ;

Kolshorn, Heinz ;

Anke, Timm ;

Opatz, Till .

JOURNAL OF ORGANIC CHEMISTRY, 2010, 75 (09) :2955-2961

← 1 2 3 →