Nitrogen doped porous carbon as excellent dual anodes for Li- and Na-ion batteries

被引:160
|
作者
Yan, Zhanheng [1 ]
Yang, Qin-Wen [2 ]
Wang, Qinghong [3 ]
Ma, Jianmin [1 ,4 ]
机构
[1] Hunan Univ, Sch Phys & Elect, Changsha 410082, Hunan, Peoples R China
[2] Hunan Univ, Coll Mech & Vehicle Engn, State Key Lab Adv Design & Mfg Vehicle Body, Changsha 410082, Hunan, Peoples R China
[3] Jiangsu Normal Univ, Sch Chem & Mat Sci, Jiangsu Key Lab Green Synthet Chem Funct Mat, Xuzhou 221116, Jiangsu, Peoples R China
[4] Zhengzhou Univ, Key Lab Mat Proc & Mold, Minist Educ, Zhengzhou 450002, Peoples R China
基金
中国国家自然科学基金;
关键词
Nitrogen doping; Carbon; Anode; Lithium-ion batteries; Sodium-ion batteries; LITHIUM-ION; CATHODE MATERIALS; ORGANIC FRAMEWORK; AMORPHOUS-CARBON; BIOMASS; GRAPHENE; STORAGE; NETWORKS; LEAVES; HOLLOW;
D O I
10.1016/j.cclet.2019.11.002
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Biomass-derived carbon materials have obtained great attention due to their sustainability, easy availability, low cost and environmentally benign. In this work, bamboo leaves derived nitrogen doped hierarchically porous carbon have been efficiently synthesized via an annealing approach, followed by an etching process in HF solution. Electrochemical measurements demonstrate that the unique porous structure, together with the inherent high nitrogen content, endow the as-derived carbon with excellent lithium/sodium storage performance. The porous carbon annealed at 700 degrees C presents outstanding rate capability and remarkable long-term stability as anodes for both lithium-ion batteries and sodium-ion batteries. The optimized carbon delivers a high discharge capacity of 450 mAh/g after 500 cycles at the current density of 0.2 A/g for LIBs, and a discharge capacity of 180 mAh/g after 300 cycles at the current density of 0.1 A/g for SIBs (C) 2019 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:583 / 588
页数:6
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