Non-isoprenoid macrocyclic glycerol diethers associated with authigenic carbonates

被引:11
作者
Baudrand, Marion [1 ]
Grossi, Vincent [1 ]
Pancost, Richard [2 ]
Aloisi, Giovanni [1 ]
机构
[1] Univ Lyon 1, CNRS, UMR5125, F-69622 Villeurbanne, France
[2] Univ Bristol, Sch Chem, Bristol Biogeochem Res Ctr, Organ Geochem Unit, Bristol BS8 1TS, Avon, England
关键词
METHANOCOCCUS-JANNASCHII; LIPIDS; MEMBRANE; BACTERIA; TETRAETHER; SULFIDE; ARCHAEA; METHANE; ALKANES; ACID;
D O I
10.1016/j.orggeochem.2010.09.002
中图分类号
P3 [地球物理学]; P59 [地球化学];
学科分类号
0708 ; 070902 ;
摘要
A series of novel non-isoprenoid macrocyclic glycerol diethers (McDGs) has been identified in authigenic carbonates formed from marine evaporites in Spain (Lorca Basin) and Egypt (Gemsa). They contain a C-32 diabolic acid-derived alkyl moiety (i.e. 15,16-dimethyltriacontane), with some components bearing additional methyl branching at C-7 and/or C-24, and show a similar distribution at each sampling site. These McGDs are suggested to have been synthesized by some extremophilic (thermophilic and/or halophilic) bacteria. Compound specific delta C-13 data indicate distinct carbon cycling by bacteria and archaea at both sites. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1341 / 1344
页数:4
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