Carborane-Bodipy scaffolds for through space energy transfer

被引：44

作者：

Ziessel, Raymond ^{[1
]}

Ulrich, Gilles ^{[1
]}

Olivier, Jean Hubert ^{[1
]}

Bura, Thomas ^{[1
]}

Sutter, Alexandra ^{[1
]}

机构：

[1] ECPM ULP, LCOSA, CNRS, F-67087 Strasbourg 02, France

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 42期

关键词：

NONLINEAR-OPTICAL MATERIALS; DYES; DERIVATIVES; CHEMISTRY; METALLACARBORANES; FLUORESCENCE; BORANES; POLYMER; DYADS;

D O I：

10.1039/c0cc02656e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Use of a closo-1,12-dicarbadecaborane backbone to link two different organic dyes separated by ca. 37 angstrom promotes exclusive through space electronic energy transfer with an efficiency of 81 to 87% with Stoke shifts between 4750 and 2800 cm(-1) depending on the pH.

引用

页码：7978 / 7980

页数：3

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