Synthesis and Properties of Polymers with an Organosilicon-Acetylene Backbone

被引：9

作者：

Budy, Stephen M. ^{[1
]}

Son, David Y. ^{[1
]}

机构：

[1] Southern Methodist Univ, Dept Chem, Dallas, TX 75275 USA

来源：

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2018年 / 28卷 / 05期

关键词：

Silicon-containing; Diacetylene; Arylacetylene; Resin; Thermoset; Thermal stability; HOLE-TRANSPORTING PROPERTIES; HIGHLY CONDUCTING PROPERTIES; RING-OPENING POLYMERIZATION; TRANSITION-METAL GROUPS; PI-CONJUGATED POLYMERS; POLYUNSATURATED ORGANOSILICON; THERMAL-PROPERTIES; DIACETYLENE POLYMERS; HEAT-RESISTANT; PRECERAMIC POLYMERS;

D O I：

10.1007/s10904-018-0854-3

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Acetylene- and diacetylene-containing organosilicon polymers continue to be of great interest in academia, government, and industry due to their high thermo-oxidative stability combined with excellent solubility and processability characteristics. Progress in this field over the past 30 years is reported herein. We present and discuss the synthesis, characterization, and structure-property relationships related to these materials. Furthermore, properties for specific applications of these polymers are briefly summarized, such as absorption and emission spectroscopy, composite mechanical analysis, four-probe conductivity measurements, and electroluminescence.

引用

页码：1673 / 1687

页数：15

共 108 条

[1] Multilayer electroluminescent device using organosilicon polymer as hole transport layer [J].

Adachi, A ;

Manhart, SA ;

Okita, K ;

Kido, JJ ;

Ohshita, J ;

Kunai, A .

SYNTHETIC METALS, 1997, 91 (1-3) :333-334

[2]

Armistead JP, 2000, APPL ORGANOMET CHEM, V14, P253, DOI 10.1002/(SICI)1099-0739(200005)14:5<253::AID-AOC987>3.0.CO

[3]

2-M

[4]

Baklanova NI, 2001, POLYM SCI SER A+, V43, P463

[5] Diacetylene-terminated diacetylene-containing polysiloxanes [J].

Beckham, HW ;

Keller, TM .

JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (12) :3363-3365

[6] MICROSTRUCTURAL ANALYSIS OF POLYSILAPROPYNYLENE COPOLYMERS BY C-13 AND SI-29 NUCLEAR-MAGNETIC-RESONANCE [J].

BORTOLIN, R ;

BROWN, SSD ;

PARBHOO, B .

MACROMOLECULES, 1990, 23 (09) :2465-2469

[7]

Bortolin R., 1988, J CHEM SOC CHEM COMM, V1079

[8] NEW POLY[(SILYLENE)DIACETYLENES] AND POLY[(GERMYLENE)DIACETYLENES] - SYNTHESIS AND CONDUCTIVE PROPERTIES [J].

BREFORT, JL ;

CORRIU, RJP ;

GERBIER, P ;

GUERIN, C ;

HENNER, BJL ;

JEAN, A ;

KUHLMANN, T ;

GARNIER, F ;

YASSAR, A .

ORGANOMETALLICS, 1992, 11 (07) :2500-2506

[9] Steady-state and time-resolved spectroscopic characteristics of novel silicon-containing organopolymers [J].

Bushuk, SB ;

Douglas, WE ;

Kalvinkovskaya, JA ;

Klapshina, LG ;

Rubinov, AN ;

Bushuk, BA ;

Stupak, AP .

JOURNAL OF FLUORESCENCE, 2003, 13 (04) :331-338

[10] Synthesis, curing behavior and thermal properties of silicon-containing hybrid polymers with Si-CC units [J].

Chen, Mingfeng ;

Xiong, Pulan ;

Zhou, Quan ;

Ni, Lizhong ;

Wang, Gengchao .

POLYMER INTERNATIONAL, 2014, 63 (08) :1531-1536

← 1 2 3 4 5 6 7 8 9 10 →