Synthesis and characterization of novel porphyrin Schiff bases

被引:30
作者
Wang, Lei [1 ]
Feng, Yaqing [1 ]
Xue, Jinqiang [1 ]
Li, Yukun [1 ]
机构
[1] Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China
关键词
porphyrin Schiff base; styryl; energy transfer;
D O I
10.2298/JSC0801001W
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Novel porphyrin Schiff bases were synthesized by a simple Schiff base condensation in refluxing toluene between 5-(4-aminophenyl)-10,15,20-triphenylporphyrin (ATTP) 3 and styryl aldehydes 4-6 or p-halobenzaldehydes 7-9. The newly synthesized porphyrin Schiff bases were characterized on the basis of their chemical properties and spectral data. A good intramolecular energy transfer from the styryl unit to the porphyrin moiety was found.
引用
收藏
页码:1 / 6
页数:6
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