Hybridized exciton-plasmon polaritons in nanostructured silver films

被引：0

作者：

Cade, Nic ^{[1
]}

Ritman-Meer, Tom ^{[1
]}

Richards, David ^{[1
]}

机构：

[1] Kings Coll London, Dept Phys, London WC2R 2LS, England

来源：

NANOPHOTONICS III | 2010年 / 7712卷

关键词：

Polariton; strong coupling; Raman; SERS; ENHANCED RAMAN-SCATTERING; SURFACE-PLASMONS; NANOPARTICLES; SPECTROSCOPY; FLUORESCENCE; MICROCAVITY; ASSEMBLIES; RESONANCES; PARTICLES; MOLECULES;

D O I：

10.1117/12.852551

中图分类号：

TM [电工技术]; TN [电子技术、通信技术];

学科分类号：

0808 ; 0809 ;

摘要：

We report on the resonant coupling between localized surface plasmon resonances (LSPRs) in nanostructured Ag films, and an adsorbed monolayer of Rhodamine 6G dye. Hybridization of the plasmons and molecular excitons creates new coupled polaritonic modes, which have been tuned by varying the LSPR wavelength. The resulting polariton dispersion curve shows an anticrossing behavior which is very well fit by a simple coupled-oscillator Hamiltonian, giving a giant Rabi-splitting energy of similar to 400 meV. The strength of this coupling is shown to be proportional to the square root of the molecular density. The Raman spectra of R6G on these films show an enhancement of many orders of magnitude due to surface enhanced scattering mechanisms; we find a maximum signal when a polariton mode lies in the middle of the Stokes shifted emission band.

引用

页数：7