A convenient method for the preparation of inverted tert-alkyl carboxylates from chiral tert-alcohols by a new type of oxidation-reduction, condensation using 2,6-dimethyl-1,4-benzoquinone

被引：74

作者：

Mukaiyama, T

Shintou, T

Fukumoto, K

机构：

[1] Kitasato Inst, Ctr Basic Res, Kita Ku, Tokyo 1140003, Japan

[2] Kitasato Univ, Inst Life Sci, Minato Ku, Tokyo 1088641, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 35期

关键词：

D O I：

10.1021/ja0303844

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oxidation-reduction condensation using in situ-formed alkoxydiphenylphosphines, 2,6-dimethyl-1,4-benzoquinone, and carboxylic acids provided a new and efficient method for the preparation of inverted tert-alkyl carboxylates from various chiral tertiary alcohols. Copyright © 2003 American Chemical Society.

引用

页码：10538 / 10539

页数：2

共 18 条

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