Fabrication of three dimensional (3D) hierarchical Ag/WO3 flower-like catalyst materials for the selective oxidation of m-xylene to isophthalic acid

被引：47

作者：

Acharyya, Shankha S. ^{[1
]}

Ghosh, Shilpi ^{[1
]}

Bal, Rajaram ^{[1
]}

机构：

[1] CSIR, Indian Inst Petr, Catalyt Convers & Proc Div, Dehra Dun, Uttar Pradesh, India

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 27期

关键词：

P-XYLENE; OXIDE; NANOSTRUCTURE; NANOWIRES; NANORODS; GROWTH;

D O I：

10.1039/c5cc00351b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A three dimensional (3D) hierarchical silver supported tungsten oxide flower-like microsphere catalyst has been fabricated using a cationic surfactant CTAB. It was found that the crystal-splitting mechanism plays a key role in the formation of this flower-like structure. This catalyst was proved to be highly effective in the liquid phase selective oxidation of m-xylene to isophthalic acid.

引用

页码：5998 / 6001

页数：4

共 25 条

[1] Fabrication of Three-Dimensional (3D) Raspberry-Like Copper Chromite Spinel Catalyst in a Facile Hydrothermal Route and Its Activity in Selective Hydroxylation of Benzene to Phenol [J].

Acharyya, Shankha S. ;

Ghosh, Shilpi ;

Bal, Rajaram .

ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (16) :14451-14459

[2] Chemistry and properties of nanocrystals of different shapes [J].

Burda, C ;

Chen, XB ;

Narayanan, R ;

El-Sayed, MA .

CHEMICAL REVIEWS, 2005, 105 (04) :1025-1102

[3] Self-assembled vanadium pentoxide (V2O5) hollow microspheres from nanorods and their application in lithium-ion batteries [J].

Cao, AM ;

Hu, JS ;

Liang, HP ;

Wan, LJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (28) :4391-4395

[4] Growth and field emission properties of cactus-like gallium oxide nanostructures [J].

Cao, Chuanbao ;

Chen, Zhuo ;

An, Xiaoqiang ;

Zhu, Hesun .

JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (01) :95-98

[5] Self-assembled porous 3D flowerlike β-In2S3 structures:: Synthesis, characterization, and optical properties [J].

Chen, Li-Yong ;

Zhang, Zu-De ;

Wang, Wei-Zhi .

JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (11) :4117-4123

[6] Design of 3-Dimensionally Self-Assembled CeO2 Nanocube as a Breakthrough Catalyst for Efficient Alkylarene Oxidation in Water [J].

Deori, Kalyanjyoti ;

Gupta, Dinesh ;

Saha, Basudeb ;

Deka, Sasanka .

ACS CATALYSIS, 2014, 4 (09) :3169-3179

[7] Room temperature selective oxidation of aniline to azoxybenzene over a silver supported tungsten oxide nanostructured catalyst [J].

Ghosh, Shilpi ;

Acharyya, Shankha S. ;

Sasaki, Takehiko ;

Bal, Rajaram .

GREEN CHEMISTRY, 2015, 17 (03) :1867-1876

[8] Preparation of silver-tungsten nanostructure materials for selective oxidation of toluene to benzaldehyde with hydrogen peroxide [J].

Ghosh, Shilpi ;

Acharyya, Shankha S. ;

Tripathi, Deependra ;

Bal, Rajaram .

JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (38) :15726-15733

[9] Selective Oxidation of Propylene to Propylene Oxide over Silver-Supported Tungsten Oxide Nanostructure with Molecular Oxygen [J].

Ghosh, Shilpi ;

Acharyya, Shankha S. ;

Tiwari, Ritesh ;

Sarkar, Bipul ;

Singha, Rajib K. ;

Pendem, Chandrashekar ;

Sasaki, Takehiko ;

Bal, Rajaram .

ACS CATALYSIS, 2014, 4 (07) :2169-2174

[10] Selective oxidation of cyclohexene to adipic acid over silver supported tungsten oxide nanostructured catalysts [J].

Ghosh, Shilpi ;

Acharyya, Shankha Shubhra ;

Adak, Shubhadeep ;

Konathala, L. N. Sivakumar ;

Sasaki, Takehiko ;

Bal, Rajaram .

GREEN CHEMISTRY, 2014, 16 (05) :2826-2834

← 1 2 3 →